methyl o-(dimethylstibino)phenyl telluride

Base Information

• Chemical Name: methyl o-(dimethylstibino)phenyl telluride
• CAS No.: 120058-46-0
• Molecular Formula: C₉H₁₃SbTe
• Molecular Weight: 370.552
• Mol file: 120058-46-0.mol

Synonyms:

Chemical Property of methyl o-(dimethylstibino)phenyl telluride

Chemical Property:

Purity/Quality:

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Technology Process of methyl o-(dimethylstibino)phenyl telluride

There total 1 articles about methyl o-(dimethylstibino)phenyl telluride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

(o-bromophenyl)dimethylstibine (34666-93-8) + dimethyl ditelluride (20334-43-4) → methyl o-(dimethylstibino)phenyl telluride (120058-46-0)

Guidance literature:

With n-butyllithium; In diethyl ether; all manipulations under dry N2; adding n-BuLi in Et2O to a soln. of (o-bromophenyl)dimethylstibine in dry Et2O (-63°C), stirring (3 h, -63°C), warming to room temp., adding dropwise Me2Te2, standing (2 h), adding H2O; extg. (Et2O), drying extract (over MgSO4, 16 h), removing solvent (vacuum), fractionating residue, chromy. of fraction boiling at 144°C (0.3 Torr) (silica gel, exclusion of air, petroleum ether, 40 - 60°C);

DOI:10.1021/om00107a028

upstream raw materials:

(o-bromophenyl)dimethylstibine

dimethyl ditelluride