mer-(ruthenium)Cl₂(Cyttp)

Base Information

• Chemical Name: mer-(ruthenium)Cl₂(Cyttp)
• CAS No.: 84623-42-7
• Molecular Formula: C₃₆H₆₁Cl₂P₃Ru
• Molecular Weight: 758.778
• Mol file: 84623-42-7.mol

Synonyms:

Chemical Property of mer-(ruthenium)Cl₂(Cyttp)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-(ruthenium)Cl₂(Cyttp)

There total 3 articles about mer-(ruthenium)Cl₂(Cyttp) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

dichlorotris(triphenylphosphine)ruthenium(II) (15529-49-4,41756-81-4) + Cyttp (70786-89-9) → RuCl2(Cyttp) (84623-42-7,132561-53-6)

Guidance literature:

In benzene; ligand soln. added to complex in C6H6, stirred for 1h; concd. (vac.), chromd. (Al2O3, C6H6), concd., pptd. (hexane), washed with hexane, dried (vac.); elem. anal.;

DOI:10.1021/om00078a001

Reference yield: 81.6%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + Cyttp (70786-89-9) → RuCl2(Cyttp) (84623-42-7,132561-53-6)

Guidance literature:

In acetone; stirring at room temperature for 30 min. in argon atmosphere; filtration, washing, drying;

Reference yield: 81.6%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + Cyttp (70786-89-9) → mer-(ruthenium)Cl2(Cyttp) (84623-42-7,132561-53-6)

Guidance literature:

In acetone; Stirring (Ar, room temp., 30 min).; Filtn., washing (acetone), drying in vac. overnight, elem. anal.;

DOI:10.1016/S0020-1693(00)91914-5

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

Cyttp

dichlorotris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

RuH₂(H₂)(Cyttp)

mer-(ruthenium)Cl₂(acetonitrile)(Cyttp)

trans-RuCl₂(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)

RuCl₂(SO₂)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)