[W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

Base Information

Chemical Name:[W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]
CAS No.:1379006-03-7
Molecular Formula:C₃₂H₁₂BF₂₄*C₄₃H₃₅O₃W
Molecular Weight:1646.82
Hs Code.:

Synonyms:

Suppliers and Price of [W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

Chemical Property:

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Technology Process of [W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

There total 1 articles about [W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1006912-59-9
[(tungsten)(hydride)(pentabenzylcyclopentadienyl)(CO)3]

: triphenylmethylium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

: 1379006-03-7
[W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

Guidance literature:: In dichloromethane; byproducts: Ph3CH; (N2); using Schlenk techniques; addn. dropwise soln. of Ph3C(B(C6H3(CF3)2)4) in CH2Cl2 to soln. of W(C5(CH2Ph)5)H(CO)3 in CH2Cl2, stirring at 0°C for 2 h and then at room temp. for 3 h; removal of solvent under vac., washing with n-hexane, drying under vac.;elem. anal.;
DOI:10.1021/om300070m

Reference yield: 99.0%

: 201230-82-2
carbon monoxide

: 1379006-03-7
[W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

: 1379006-08-2
[W(CO)4(η5-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

Guidance literature:: In dichloromethane-d2; (N2); using Schlenk techniques; transferring of soln. of W(C5(CH2Ph)5)(CO)3(B(C6H3(CF3)2)4) in CD2Cl2 in NMR tube, freezing in liquid N2, evacuating on vac. line, sparging with CO, warming to room temp. for 1 h; evapn. of solvent under vac.; elem. anal.;
DOI:10.1021/om300070m

Reference yield: 45.0%

: 1379006-03-7
[W(CO)3(η5:η2-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

: 7732-18-5
water

: [W(CO)3(H2O)(η5-pentabenzylcyclopentadienyl)][B(3,5-C6H3(CF3)2)4]

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; dissolving of W(C5(CH2Ph)5)(CO)3(B(C6H3(CF3)2)4) in CH2Cl2, addn. of an excess of degassed H2O at room temp. with vigorous stirring for 0.5 h; evapn. of solvent under vac.;
DOI:10.1021/om300070m