Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene

Base Information

Chemical Name:Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene
CAS No.:1444200-40-1
Molecular Formula:C₄₄H₅₈S₆Sn₂
Molecular Weight:1016.76
Hs Code.:

Synonyms:

Suppliers and Price of Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
[4,8-Bis[5-(2-ethylhexyl)thieno[3,2-b]thiophen-2-yl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]bis(trimethylstannane) >97.0%(HPLC)
200mg
$ 427.00

AK Scientific
[4,8-Bis[2-(2-ethylhexyl)thieno[3,2-b]thiophen-5-yl]-2-trimethylstannylthieno[2,3-f][1]benzothiol-6-yl]-trimethylstannane
200mg
$ 650.00

Total 12 raw suppliers

Chemical Property of Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene

Chemical Property:

Boiling Point:882.9±75.0 °C(Predicted)

Purity/Quality:

99%, ^*data from raw suppliers

[4,8-Bis[5-(2-ethylhexyl)thieno[3,2-b]thiophen-2-yl]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl]bis(trimethylstannane) >97.0%(HPLC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene

There total 3 articles about Ditrimethyltinethylhexyl-thienothiophene-benzodithiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1494614-30-0
4,8-bis((2-ethylhexyl)thieno[3,2-b]thiophene)-benzo[1,2-b:4,5-b′]dithiophene

: 1066-45-1
trimethyltin(IV)chloride

: 1444200-40-1
2,6-bis(trimethyltin)-4,8-bis((2-ethylhexyl)thieno[3,2-b]thiophene)-benzo[1,2-b:4,5-b′]dithiophene

Guidance literature:: With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; pentane; at -78 - 20 ℃; for 14h; Inert atmosphere;
DOI:10.1021/cm4035903

Reference yield:

: 251-41-2
thieno[3,2-b]thiophene

: 1444200-40-1
2,6-bis(trimethyltin)-4,8-bis((2-ethylhexyl)thieno[3,2-b]thiophene)-benzo[1,2-b:4,5-b′]dithiophene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1.33 h / -78 - 20 °C / Inert atmosphere

1.2: 12 h / 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; pentane / 2 h / 50 °C / Inert atmosphere

2.2: 1 h / 50 °C / Inert atmosphere

2.3: 2 h / 20 °C / Inert atmosphere

3.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / tetrahydrofuran; pentane / 14 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; pentane;
DOI:10.1021/cm4035903

Reference yield:

: 18908-66-2
3-bromomethylheptane

: 1444200-40-1
2,6-bis(trimethyltin)-4,8-bis((2-ethylhexyl)thieno[3,2-b]thiophene)-benzo[1,2-b:4,5-b′]dithiophene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1.33 h / -78 - 20 °C / Inert atmosphere

1.2: 12 h / 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; pentane / 2 h / 50 °C / Inert atmosphere

2.2: 1 h / 50 °C / Inert atmosphere

2.3: 2 h / 20 °C / Inert atmosphere

3.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / tetrahydrofuran; pentane / 14 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; hexane; pentane;
DOI:10.1021/cm4035903