methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

Base Information

• Chemical Name: methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)
• CAS No.: 179930-23-5
• Molecular Formula: C₄₉H₃₉N₅O₂Ru
• Molecular Weight: 830.951
• Mol file: 179930-23-5.mol

Synonyms:

Chemical Property of methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

There total 1 articles about methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(carbonyl-κC)(methanol-κO)(5,10,15,20-tetra-p-tolylporphyrinato-κ(4)N)ruthenium(II) (179930-29-1) + nitrogen(II) oxide (10102-43-9) → methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) (179930-23-5)

Guidance literature:

With DBU; In dichloromethane; passing N2 through soln. of Ru-complex and DBU for 45 min, then passing NO with stirring for 20 min; purging with N2, crystn. on concn. (reduced pressure), collection (filtration), washing (cold MeOH), drying (vac.); can be recrystallized (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/ic980182m

Reference yield: 99.0%

methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) (179930-23-5) + hydrogen sulfide (7783-06-4) → sulfhydro(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) (215526-07-1)

Guidance literature:

In toluene; absence of air and moisture; bubbling H2S for 10 min; evapn. (vac.), recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1021/ic980182m

Reference yield: 82.0%

hexafluorophosphoric acid + methoxide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II) (179930-23-5) + water (7732-18-5) → [aquo(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)][hexafluorophosphate] (215526-05-9)

Guidance literature:

In dichloromethane; addn. of 60% aq. HPF6 to Ru-complex, stirring for 5 min; evapn. (vac.), drying (2E-5 Torr, 24 h), recrystn. (CH2Cl2/hexane), collection (filtration), washing (hexane, pentane), drying (vac.); elem. anal.;

DOI:10.1021/ic980182m

upstream raw materials:

(carbonyl-κC)(methanol-κO)(5,10,15,20-tetra-p-tolylporphyrinato-κ(4)N)ruthenium(II)

nitrogen(II) oxide

Downstream raw materials:

[aquo(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)][hexafluorophosphate]

imidazolide(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

nitrosyl(p-thiocresolate)(meso-tetra-p-tolylporphyrinato)ruthenium(II)

sulfhydro(nitrosyl)(meso-tetra-p-tolylporphyrinato)ruthenium(II)