trans-bis(triphenylphosphino)Pt(CF₃)Cl

Base Information

Chemical Name:trans-bis(triphenylphosphino)Pt(CF₃)Cl
CAS No.:71581-10-7
Molecular Formula:C₃₇H₃₀ClF₃P₂Pt
Molecular Weight:824.121
Hs Code.:

trans-bis(triphenylphosphino)Pt(CF<sub>3</sub>)Cl

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Chemical Property of trans-bis(triphenylphosphino)Pt(CF₃)Cl

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Technology Process of trans-bis(triphenylphosphino)Pt(CF₃)Cl

There total 28 articles about trans-bis(triphenylphosphino)Pt(CF₃)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 176900-85-9
Pt(CF₃)(P(C₆H₅)3)2(NCCH₂CH(CO₂CH₃)NHCOOCH₂C₆H₅)⁽¹⁺⁾*BF₄^(1-)=[Pt(CF₃)(P(C₆H₅)3)2(NCCH₂CH(CO₂CH₃)NHCOOCH₂C₆H₅)]BF₄

: 107-07-3
2-chloro-ethanol

: 71581-10-7
trans-bis(triphenylphosphino)Pt(CF₃)Cl

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; byproducts: Boc-NH-CH(CO2Me)CH2(cyclo-C3H4ON); N2-atmosphere; treatment of ClCH2CHOH (in THF) with BuLi (in hexane), addn. of Pt-complex, standing for 23 h at room temp. (pptn.); collection (filtration in air);
DOI:10.1016/0020-1693(96)05126-2

Reference yield: 49.0%

: Pt(CF₃)(NCC₆H₅)[P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)*0.5CH₂Cl₂=[Pt(CF₃)(NCC₆H₅)P₂(C₆H₅)6]BF₄*0.5CH₂Cl₂

: 107-07-3
2-chloro-ethanol

: 71581-10-7
trans-bis(triphenylphosphino)Pt(CF₃)Cl

: 154648-73-4
Pt(CF₃)[NC(C₆H₅)OCH₂CH₂][P(C₆H₅)3]2⁽¹⁺⁾*BF₄^(1-)=[Pt(CF₃)[NC(C₆H₅)OCH₂CH₂]P₂(C₆H₅)6]BF₄

Guidance literature:: With n-C₄H₉Li; In tetrahydrofuran; hexane; Treating soln. of ClC2H4OH in THF (0°C) with n-BuLi (n-hexane) followed by Pt-compd., stirring of suspn. at 0°C for 20 min, and then reducing of volume.; Addn. of n-pentane, filtn., drying of soln., treating with Et2O. IR andGLC/MS spectra show presence of free oxazoline. Sepn. of Pt-compds. by taking advantage of the higher solubility of chloro complex in benzene. Elem. anal. of Pt-oxazoline compd.;

Reference yield: 49.0%

: {Pt(CF₃)(NCC₆H₅)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)={Pt(CF₃)(NCC₆H₅)(P(C₆H₅)3)2}BF₄

: 627-30-5
1-chloro-3-hydroxypropane

: 71581-10-7
trans-bis(triphenylphosphino)Pt(CF₃)Cl

: {Pt(CF₃)(NC(C₆H₅)OCH₂CH₂CH₂)(P(C₆H₅)3)2}⁽¹⁺⁾*BF₄^(1-)*0.5CH₂Cl₂={Pt(CF₃)(NC(C₆H₅)OCH₂CH₂CH₂)(P(C₆H₅)3)2}BF₄*0.5CH₂Cl₂

Guidance literature:: With n-butyl lithium; CH₂Cl₂; In tetrahydrofuran; addn. of n-C4H9Li (0.84 mmol) in n-hexane and solid trans-(Pt(CF3)(NCPh)(PPh3)2)BF4 (0.76 mmol) to THF soln. of ClC3H6OH (5.98 mmol) at 0°C; stirring for 5 min at 0°C;; concg., addn. of Et2O (pptn.); filtering off, washing with warm C6H6; dissolving solid residue in CH2Cl2; addn. of Et2O (pptn.); filtering off, washing with Et2O and drying under vac.; elem. anal.; isolation of (Pt(CF3)Cl(PPh3)2) from C6H6-filtrate;;
DOI:10.1016/0020-1693(94)03850-3