2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl

Base Information

• Chemical Name: 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl
• CAS No.: 1616765-12-8
• Molecular Formula: C₂₇H₁₅F₃NO₄PW
• Molecular Weight: 689.239
• Mol file: 1616765-12-8.mol

Synonyms:

Chemical Property of 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl

There total 7 articles about 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tungsten hexacarbonyl (14040-11-0) + 2-(2-pyridyl)-4-(4-trifluoromethylphenyl)-6-phenylphosphinine (1616765-00-4) → 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl (1616765-12-8)

Guidance literature:

In tetrahydrofuran-d8; UV-irradiation; Inert atmosphere; Sealed tube;

DOI:10.1039/c8dt01441h

Reference yield:

3-(4-(trifluoromethyl)phenyl)-1-phenylprop-2-en-1-one (61637-11-4) → 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl (1616765-12-8)

Guidance literature:

Multi-step reaction with 4 steps

1: sodium hydroxide / 0.17 h / Milling

2: 3 h / 80 °C / Inert atmosphere

3: Tris(trimethylsilyl)phosphane / acetonitrile / 6 h / 85 °C / Inert atmosphere

4: tetrahydrofuran-d8 / UV-irradiation

With Tris(trimethylsilyl)phosphane; sodium hydroxide; In tetrahydrofuran-d8; acetonitrile;

DOI:10.1039/c4cc03469d

Reference yield:

2-(2-pyridyl)-4-(4-trifluoromethylphenyl)-6-phenylpyrylium tetrafluoroborate → 2-(2-pyridyl)-4-phenyl-6-(4-trifluoromethylphenyl)phosphinine-P,N-tungsten tetracarbonyl (1616765-12-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Tris(trimethylsilyl)phosphane / acetonitrile / 6 h / 85 °C / Inert atmosphere

2: tetrahydrofuran-d8 / UV-irradiation

With Tris(trimethylsilyl)phosphane; In tetrahydrofuran-d8; acetonitrile;

DOI:10.1039/c4cc03469d

upstream raw materials:

tungsten hexacarbonyl

2-(2-pyridyl)-4-(4-trifluoromethylphenyl)-6-phenylphosphinine

3-(4-(trifluoromethyl)phenyl)-1-phenylprop-2-en-1-one

acetophenone