<(Diphenylmethyliden)amino>dimethylphosphin

Base Information

• Chemical Name: <(Diphenylmethyliden)amino>dimethylphosphin
• CAS No.: 33027-76-8
• Molecular Formula: C₁₅H₁₆NP
• Molecular Weight: 241.272
• Mol file: 33027-76-8.mol

Synonyms:

Chemical Property of <(Diphenylmethyliden)amino>dimethylphosphin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of <(Diphenylmethyliden)amino>dimethylphosphin

There total 1 articles about <(Diphenylmethyliden)amino>dimethylphosphin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzophenone imine (1013-88-3) + chlorodimethylphosphine (811-62-1) → <(Diphenylmethyliden)amino>dimethylphosphin (33027-76-8)

Guidance literature:

With triethylamine; In diethyl ether;

Reference yield: 85.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + <(Diphenylmethyliden)amino>dimethylphosphin (33027-76-8) → [RuCl(μ-Cl)(PPh3)(C6H4(PMe2)C(Ph)NH)]2 (1392015-10-9)

Guidance literature:

In further solvent(s); (N2) soln. Ru complex and Me2PN=CPh2 in bromobenzene was heated overnight at 140°C; soln. was filtered hot, ppt. was washed with bromobenzene and pentane; elem. anal.;

DOI:10.1039/c2dt30505d

Reference yield: 67.0%

carbon disulfide (75-15-0,12122-00-8) + <(Diphenylmethyliden)amino>dimethylphosphin (33027-76-8) → 3-(Diphenylmethyliden)-3,4-dihydro-2,2-dimethyl-4-thioxo-2H-1,3,2λ5-thiazaphosphet-3-ium-2-id (124254-24-6)

Guidance literature:

In diethyl ether;

DOI:10.1002/hlca.19890720118

upstream raw materials:

Benzophenone imine

chlorodimethylphosphine

Downstream raw materials:

2,2-dimethyl-5,5-diphenyl-4,5-dihydro-3H-2λ⁵-[1,2]azaphosphole-4-carboxylic acid methyl ester

2,2-dimethyl-5,5-diphenyl-5H-2λ⁵-[1,2]azaphosphole-3,4-dicarboxylic acid dimethyl ester

C₁₆H₁₉NP⁽¹⁺⁾*I^(1-)

3-(Diphenylmethyliden)-3,4-dihydro-2,2-dimethyl-4-thioxo-2H-1,3,2λ⁵-thiazaphosphet-3-ium-2-id

Refernces