exo-2-Chloro-7,7-dimethylnorbornane

Base Information

• Chemical Name: exo-2-Chloro-7,7-dimethylnorbornane
• CAS No.: 22768-98-5
• Molecular Formula: C₉H₁₅Cl
• Molecular Weight: 158.671
• Mol file: 22768-98-5.mol

Synonyms:

Chemical Property of exo-2-Chloro-7,7-dimethylnorbornane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of exo-2-Chloro-7,7-dimethylnorbornane

There total 6 articles about exo-2-Chloro-7,7-dimethylnorbornane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7,7-dimethylbicyclo<2.2.1>heptan-exo-2-ol (111821-64-8) → 7,7-dimethyl-exo-2-norbonylchloride (22768-98-5)

Guidance literature:

With thionyl chloride; In pentane;

DOI:10.1021/ja01080a041

Reference yield:

→ 2-chloro-7,7-dimethyl-norbornane (22768-98-5,54655-21-9,63303-54-8) + 5-chloro-2,2-dimethyl-norbornane (57745-24-1)

Guidance literature:

With hydrogenchloride; diethyl ether; Kuehlung;

Reference yield:

phosphorus pentachloride (10026-13-8,874483-75-7) + 3,3-dimethylbicyclo<2.2.1>heptan-endo-2-ol (640-54-0) → 2-chloro-7,7-dimethyl-norbornane (22768-98-5,54655-21-9,63303-54-8) + 3,3-Dimethyl-exo-norbornylchlorid (22768-97-4) + 5-chloro-2,2-dimethyl-norbornane (57745-24-1)

Guidance literature:

at 0 ℃;

upstream raw materials:

7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

phosphorus pentachloride

3,3-dimethylbicyclo<2.2.1>heptan-endo-2-ol

7,7-dimethylbicyclo<2.2.1>heptan-exo-2-ol

Downstream raw materials:

7,7-dimethyl-norbornane

Refernces

• 1、 Brown,Kawakami,Misumi. "Additions to bicyclic olefins. II. A convenient synthesis of apobornene and apocamphor.". . p. 1360 - 1363. Retrieved 2007/10/12.