Phosphorus pentachloride

Base Information Edit

Chemical Name:Phosphorus pentachloride
CAS No.:10026-13-8
Molecular Formula:Cl₅P
Molecular Weight:208.239
Hs Code.:HOSPHORUS PENTACHLORIDE PRODUCT IDENTIFICATION
European Community (EC) Number:233-060-3
ICSC Number:0544
UN Number:1806
UNII:0EX753TYDU
DSSTox Substance ID:DTXSID9033896
Nikkaji Number:J95.140D
Wikipedia:Phosphorus pentachloride
Wikidata:Q283427
ChEMBL ID:CHEMBL1465793
Mol file:10026-13-8.mol

Synonyms:PHOSPHORUS PENTACHLORIDE;10026-13-8;Phosphorus(V) chloride;Pentachlorophosphorane;Phosphorane, pentachloro-;Phosphoric chloride;Phosphorus perchloride;PCl5;Phosphorous pentachloride;Phosphorpentachlorid;Phosphoric perchloride;Fosforpentachloride;Pentachlorophosphorus;Pieciochlorek fosforu;Phosphorus chloride (PCl5);Pentachloro-lambda5-phosphane;Phosphoruspentachloride;Fosforo(pentacloruro di);HSDB 1205;UNII-0EX753TYDU;Phosphore(pentachlorure de);Fosforpentachloride [Dutch];EINECS 233-060-3;0EX753TYDU;Phosphorpentachlorid [German];Pieciochlorek fosforu [Polish];pentachloridophosphorus;DTXSID9033896;CHEBI:30335;Fosforo(pentacloruro di) [Italian];MFCD00011439;Phosphore(pentachlorure de) [French];UN1806;pentachloro-lambda(5)-phosphane;DTXCID7013896;EC 233-060-3;(PCl5);[PCl5];Fosforpentaklorid;phosphorus pentachoride;Cl5P;Fosforano, pentacloro-;phosphorus pentachioride;phosphorus-pentachloride;phosphorus (V)-chloride;phosphorus penta-chloride;phosphorus-(V)-chloride;Cl5-P;phosphorous (V) chloride;Pentachlorure de phosphore;Fosforo (pentachloruro di);(Phosphorus pentachloride );Phosphorus pentachloride, CP;Phosphorous (V) pentachloride;CHEMBL1465793;Tox21_202530;NA1806;PHOSPHORUS PENTACHLORIDE [MI];AKOS015918493;pentakis(chloranyl)-$l^{5}-phosphane;PHOSPHORUS PENTACHLORIDE, SOLID;PHOSPHORUS PENTACHLORIDE [HSDB];NCGC00090975-01;NCGC00260079-01;PHOSPHORUS PENTACHLORIDE, (SOLID);CAS-10026-13-8;LS-107454;FT-0601937;P1612;Phosphorus pentachloride, reagent grade, 95%;Phosphorus pentachloride [UN1806] [Corrosive];Phosphorus pentachloride [UN1806] [Corrosive];A800083;Q283427;Phosphorus pentachloride, purum p.a., >=98.0% (AT)

Suppliers and Price of Phosphorus pentachloride

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Phosphorus(V) chloride, 98%
250g
$ 47.00

Strem Chemicals
Phosphorus(V) chloride, 98%
1kg
$ 143.00

Sigma-Aldrich
Phosphorus pentachloride reagent grade, 95%
5g
$ 47.70

Sigma-Aldrich
Phosphorus pentachloride purum p.a., ≥98.0% (AT)
1kg
$ 123.00

Sigma-Aldrich
Phosphorus pentachloride
8451381000
$ 143.00

Sigma-Aldrich
Phosphorus pentachloride for synthesis. CAS 10026-13-8, EC Number 233-060-3, chemical formula PCl ., for synthesis
8223401000
$ 111.00

Sigma-Aldrich
Phosphorus pentachloride for synthesis
1 kg
$ 106.37

Sigma-Aldrich
Phosphorus pentachloride purum p.a., ≥98.0% (AT)
500g
$ 104.00

Sigma-Aldrich
Phosphorus pentachloride reagent grade, 95%
1kg
$ 99.60

Sigma-Aldrich
Phosphorus pentachloride reagent grade, 95%
100g
$ 79.80

Total 53 raw suppliers

Chemical Property of Phosphorus pentachloride Edit

Chemical Property:

Appearance/Colour:Yellowish crystalline powder and scales
Vapor Pressure:0.016 hPa (20 °C)
Melting Point:179-181 °C (subl.)
Refractive Index:FLASH POINT
Boiling Point:160 °C
Flash Point:none
PSA：13.59000
Density:1.6 g/cm³
LogP:4.30870
Storage Temp.:2-8°C
Sensitive.:Moisture Sensitive
Solubility.:Soluble in carbon disulfide and carbon tetrachloride.
Water Solubility.:decomposes
XLogP3:3.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:207.815075
Heavy Atom Count:6
Complexity:37.1
Transport DOT Label:Corrosive

Purity/Quality:

99.9% ^*data from raw suppliers

Phosphorus(V) chloride, 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): T+
Hazard Codes:T+
Statements: 14-22-26-34-48/20
Safety Statements: 26-36/37/39-45-7/8

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:Toxic Gases & Vapors -> Other Toxic Gases & Vapors
Canonical SMILES:P(Cl)(Cl)(Cl)(Cl)Cl
Inhalation Risk:A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20 °C.
Effects of Short Term Exposure:The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation may cause lung oedema. The effects may be delayed. Medical observation is indicated.
Effects of Long Term Exposure:Repeated or prolonged contact with skin may cause dermatitis.
Physical Properties Yellowish-white tetragonal crystals; pungent odor; fumes in air; deliquescent; density 2.1 g/cm3; decomposes on heating; melts at 166.8°C under the pressure of its own vapor(triple point); sublimes at 160°C; critical temperature 373°C; hydrolyzes in water; soluble in carbon disulfide and carbon tetrachloride.
Uses Phosphorus pentachloride is used as a chlorinating agent in many organic syntheses, such as production of alkyl and acid chlorides. It also is a catalyst in manufacturing acetylcellulose. As catalyst in manufacture of acetylcellulose; for replacing hydroxyl groups by Cl, particularly for converting acids into acid chlorides. Phosphorus pentachloride is used as a chlorinating agent to convert acids into acid chlorides, as a dehydrating agent, and as a catalyst. Catalyst in manufacture of acetylcellulose; chlorinating and dehydrating agent

Technology Process of Phosphorus pentachloride

There total 99 articles about Phosphorus pentachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%