Acrolein 2,4-Dinitrophenylhydrazone-d3

Base Information

• Chemical Name: Acrolein 2,4-Dinitrophenylhydrazone-d3
• CAS No.: 259824-62-9
• Molecular Formula: C₉H₈N₄O₄
• Molecular Weight: 239.163
• Mol file: 259824-62-9.mol

Synonyms:

Chemical Property of Acrolein 2,4-Dinitrophenylhydrazone-d3

Chemical Property:

• Melting Point: >150°C (dec.)
• Storage Temp.: Amber Vial, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)

Purity/Quality:

95% ^*data from raw suppliers

Acrolein2,4-Dinitrophenylhydrazone-d3 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Labelled analogue of Acrolein 2,4-Dinitrophenylhydrazone, a dinitrophenylhydrazone (DNPH) derivative of an aliphatic alldehyde found in mainstream cigarette smoke.

Technology Process of Acrolein 2,4-Dinitrophenylhydrazone-d3

There total 3 articles about Acrolein 2,4-Dinitrophenylhydrazone-d3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,5,6-d3-2,4-dinitrophenylhydrazine (259824-49-2) + acrolein (107-02-8,25068-14-8) → C9H5(2)H3N4O4 (259824-62-9)

Guidance literature:

With formic acid; In acetonitrile; at 40 ℃; for 2h; Darkness;

DOI:10.1021/ac501309s

Reference yield:

d3-2,4-dinitrochlorobenzene → C9H5(2)H3N4O4 (259824-62-9)

Guidance literature:

Multi-step reaction with 2 steps

1: hydrazine; acetic acid

2: formic acid / acetonitrile / 2 h / 40 °C / Darkness

With formic acid; acetic acid; hydrazine; In acetonitrile;

DOI:10.1021/ac501309s

Reference yield:

chlorobenzene-d(5) (3114-55-4,59164-11-3) → C9H5(2)H3N4O4 (259824-62-9)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium nitrate; sulfuric acid

2: hydrazine; acetic acid

3: formic acid / acetonitrile / 2 h / 40 °C / Darkness

With formic acid; sulfuric acid; acetic acid; potassium nitrate; hydrazine; In acetonitrile;

DOI:10.1021/ac501309s

upstream raw materials:

3,5,6-d₃-2,4-dinitrophenylhydrazine

acrolein

chlorobenzene-d⁽⁵⁾