[Fe₂{μ(SeCH₂)₂N(Cbz)}(CO)₆]

Base Information

• Chemical Name: [Fe₂{μ(SeCH₂)₂N(Cbz)}(CO)₆]
• CAS No.: 1313861-39-0
• Molecular Formula: C₁₆H₁₁Fe₂NO₈Se₂
• Molecular Weight: 614.879
• Mol file: 1313861-39-0.mol

Synonyms:

Chemical Property of [Fe₂{μ(SeCH₂)₂N(Cbz)}(CO)₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Fe₂{μ(SeCH₂)₂N(Cbz)}(CO)₆]

There total 3 articles about [Fe₂{μ(SeCH₂)₂N(Cbz)}(CO)₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

PhCH2O2CN(CH2Cl)2 + (μ-Se2)(carbonyl)6diiron (76185-26-7) + lithium triethylborohydride (22560-16-3) → [Fe2{μ(SeCH2)2N(Cbz)}(CO)6] (1313861-39-0)

Guidance literature:

In tetrahydrofuran; (N2) to soln. Fe complex in THF at -78°C Et3BHLi was added, stirred at -78°C for 20 min, PhCH2OC(O)N(CH2Cl)2 was added, warmed to room temp. and stirred for 12 h; volatiles were removed in vacuo, TLC (CH2Cl2 - petroleum ether 3:1); elem. anal.;

DOI:10.1021/om200395g

Reference yield: 20.0%

PhCH2O2CN(CH2Cl)2 + [(μ-Se)2Fe2(CO)6] → [Fe2{μ(SeCH2)2N(Cbz)}(CO)6] (1313861-39-0)

Guidance literature:

[(μ-Se)2Fe2(CO)6]; With lithium triethylborohydride; In tetrahydrofuran; at -78 ℃; for 0.25h; Inert atmosphere; Schlenk technique; Glovebox;

PhCH₂O₂CN(CH₂Cl)2; In tetrahydrofuran; at 20 ℃; for 13h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c7dt03785f

Reference yield:

O-benzyl carbamate (621-84-1) → [Fe2{μ(SeCH2)2N(Cbz)}(CO)6] (1313861-39-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: potassium hydroxide / melt / 150 °C / Inert atmosphere; Schlenk technique; Glovebox

1.2: Inert atmosphere; Schlenk technique; Glovebox

2.1: lithium triethylborohydride / tetrahydrofuran / 0.25 h / -78 °C / Inert atmosphere; Schlenk technique; Glovebox

2.2: 13 h / 20 °C / Inert atmosphere; Schlenk technique; Glovebox

With lithium triethylborohydride; potassium hydroxide; In tetrahydrofuran; melt;

DOI:10.1039/c7dt03785f

upstream raw materials:

(μ-Se2)(carbonyl)6diiron

lithium triethylborohydride

O-benzyl carbamate

Downstream raw materials:

[(μ-SeCH2)2NC(O)CH2Ph]Fe2(CO)6