tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

Base Information

Chemical Name:tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane
CAS No.:185030-56-2
Molecular Formula:C₂₉H₅₀O₇Si
Molecular Weight:538.797
Hs Code.:

tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

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Chemical Property of tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

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Technology Process of tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

There total 1 articles about tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 77-76-9
2,2-dimethoxy-propane

: 185030-51-7
tert-Butyl-[(3E,5E)-(7S,9R)-9-(4-methoxy-benzyloxy)-7-methoxymethoxy-deca-3,5-dienyloxy]-dimethyl-silane

: tert-Butyl-((E)-4-{(4S,5S)-5-[(1S,3R)-3-(4-methoxy-benzyloxy)-1-methoxymethoxy-butyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-but-3-enyloxy)-dimethyl-silane

: 185030-56-2
tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

: tert-Butyl-(2-{(4R,5R)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

Guidance literature:: With AD-mix-α; Product distribution; various substrates, selectivity;
DOI:10.1021/jo961686+

Reference yield:

: 185030-56-2
tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

: 127393-89-9,147705-04-2
(4S,5S,8S,10R,E)-4,5,8-trihydroxy-10-methyl-4,5,9,10-tetrahydro-3H-oxecin-2(8H)-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) TBAF, 2.) IBX / 1.) THF, room temperature, 3 h, 2.) DMSO, room temperature, 14-20 h

2: 1.) NaClO₂, NaH₂PO₄*H₂O, 2.) NaHCO₃, DDQ / 1.) t-BuOH, 2-methyl-2-butene, H₂O, room temperature, 5 h, 2.) CH₂Cl₂, room temperature, 5 h

3: 33 percent / 2,2'-pyridyl disulfide, PPh₃, AgClO₄ / benzene / 18 h / Heating

4: 58 percent / Dowex-50 / methanol / 96 h / Ambient temperature

With sodium chlorite; sodium dihydrogenphosphate; 2,2'-dipyridyldisulphide; Dowex-50; tetrabutyl ammonium fluoride; silver perchlorate; sodium hydrogencarbonate; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In methanol; benzene;
DOI:10.1021/jo961686+

Reference yield:

: 185030-56-2
tert-Butyl-(2-{(4S,5S)-5-[(E)-(3S,5R)-5-(4-methoxy-benzyloxy)-3-methoxymethoxy-hex-1-enyl]-2,2-dimethyl-[1,3]dioxolan-4-yl}-ethoxy)-dimethyl-silane

: 185030-59-5
(3S,4S,5E,7S,9R)-3.4-(dimethylmethylenedioxy)-9-(4-methoxybenzyloxy)-7-(methoxymethoxy)-5-decenal

Guidance literature:: With tetrabutyl ammonium fluoride; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; Yield given. Multistep reaction; 1.) THF, room temperature, 3 h, 2.) DMSO, room temperature, 14-20 h;
DOI:10.1021/jo961686+