μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

Base Information

Chemical Name:μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate
CAS No.:1093375-67-7
Molecular Formula:C₄₀H₂₄F₁₂O₆P₂Pd₂
Molecular Weight:1103.4
Hs Code.:

Synonyms:

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Chemical Property of μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

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Technology Process of μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

There total 2 articles about μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: μ-(2,5-bis(diphenylphosphino)-1,4-semiquinone)-bis-palladiumhexafluoroacetylacetonate hexafluorophosphate

: 1093375-67-7
μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

Guidance literature:: With Zn; In not given; Pd complex reduced in soln. with Zn;
DOI:10.1139/V08-127

Reference yield: 35.4%

: palladium(II) hexafluoroacetylacetonate

: 1093375-70-2
(2,5-dihydroxy-1,4-phenylene)bis(diphenylphosphine)

: 1093375-67-7
μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

Guidance literature:: In toluene; ligand and Pd compd. dissolved separately in min. amt. of toluene with gentle heating; soln. of ligand added dropwise to soln. of Pd compd.; stirred for 5 min; filtered; ppt. dissolved in CH2Cl2-Et2O; filtered; elem. anal.;
DOI:10.1139/V08-127

Reference yield: 85.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 1093375-67-7
μ-(2,5-bis(diphenylphosphino)-1,4-hydroquinone)-bis-palladiumhexafluoroacetylacetonate

: μ-(2,5-bis(diphenylphosphino)-1,4-semiquinone)-bis-palladiumhexafluoroacetylacetonate hexafluorophosphate

Guidance literature:: In dichloromethane; under Ar; Pd complex dissolved in freshly distd. CH2Cl2; stirred for 10 min; AgPF6 added; vol. reduced in vac.; dry hexane added; cooled on ice for 10 min; filtered under inert atmosphere; solid washed with dry hexanes; dried in vac. for 30 min; isolated under inert atmosphere;
DOI:10.1139/V08-127