1,1'-bis(3-mercaptopropenale)ferrocene dianil

Base Information

• Chemical Name: 1,1'-bis(3-mercaptopropenale)ferrocene dianil
• CAS No.: 205487-90-7
• Molecular Formula: C₂₈H₂₄FeN₂S₂
• Molecular Weight: 508.491
• Mol file: 205487-90-7.mol

Synonyms:

Chemical Property of 1,1'-bis(3-mercaptopropenale)ferrocene dianil

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1,1'-bis(3-mercaptopropenale)ferrocene dianil

There total 2 articles about 1,1'-bis(3-mercaptopropenale)ferrocene dianil which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

Zn(Fe(C5H4C(S)CHCHO)2) + aniline (62-53-3) → 1,1'-bis(3-mercaptopropenale)ferrocene dianil (205487-90-7)

Guidance literature:

In ethanol; addn. of 2 equiv. of amine to Fe-complex suspn., stirring (room temp., 24 h), addn. of H2O; extn. into CH2Cl2, washing (1 M HCl, H2O), solvent removal, recrystn. (MeOH/CH2Cl2=3:1);

DOI:10.1016/s0020-1693(97)05892-1

Reference yield: 60.0%

hydrogenchloride (7647-01-0,15364-23-5) + sodiumsulfide nonahydrate + 1,1'-bis(1-chloro-2-formylvinyl)ferrocene (1291-86-7) + aniline (62-53-3) → 1,1'-bis(3-mercaptopropenale)ferrocene dianil (205487-90-7)

Guidance literature:

In methanol; Ar-atmosphere; slow addn. of 2 equiv. of Fe-complex to 3 equiv. of Na2S soln., stirring (room temp., 2 h), extn. into ether, addn. of CH2Cl2 to aq. layer, addn. of 1 M HCl, stirring for 30 min, addn. of amine, stirring for 1 h; extn. into CH2Cl2, washing (1 M HCl, H2O), solvent removal, recrystn. (MeOH/CH2Cl2=3:1); elem. anal.;

DOI:10.1016/s0020-1693(97)05892-1

upstream raw materials:

hydrogenchloride

1,1'-bis(1-chloro-2-formylvinyl)ferrocene

aniline