(cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium

Base Information

• Chemical Name: (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium
• CAS No.: 155022-51-8
• Molecular Formula: C₃₀H₃₁ClIrN₂P
• Molecular Weight: 678.236
• Mol file: 155022-51-8.mol

Synonyms:

Chemical Property of (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium

There total 2 articles about (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

chloro(1,5-cyclooctadiene)iridium(I) dimer + 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (144101-82-6) → (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium (155022-51-8)

Guidance literature:

In dichloromethane; a mixt. of the phosphine and Ir complex was stirred in CH2Cl2 for 10 min; molar ratio of phosphine:Ir-complex = 2:1; N2 atm.;; pptn. by addn. of n-hexane; the ppt. was separated, washed with Et2O, and dried under vac.; elem. anal.;;

DOI:10.1016/0020-1693(93)03730-X

Reference yield:

{(Ir(cycloocta-1,5-diene)Cl)2(μ-7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)} (155022-54-1) + 7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine (144101-82-6) → (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium (155022-51-8)

Guidance literature:

In dichloromethane; addn. of solid phosphine to a CH2Cl2 soln. of the Ir complex; stirring for 0.5 h; N2 atm.;; pptn. by addn. of n-hexane; elem. anal.;;

DOI:10.1016/0020-1693(93)03730-X

Reference yield: 82.0%

chloro(1,5-cyclooctadiene)iridium(I) dimer + (cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)chloroiridium (155022-51-8) → {(Ir(cycloocta-1,5-diene)Cl)2(μ-7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)} (155022-54-1)

Guidance literature:

In dichloromethane; addn. of solid (Ir(COD)Cl)2 to a soln. of the Ir-phosphine complex in CH2Cl2; stirring for about 10 min; N2 atm.;; pptn. by addn. of n-hexane; elem. anal.;;

DOI:10.1016/0020-1693(93)03730-X

upstream raw materials:

7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine

{(Ir(cycloocta-1,5-diene)Cl)2(μ-7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)}

Downstream raw materials:

(cycloocta-1,5-diene)(7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)iridium(I) perchlorate

{(Ir(cycloocta-1,5-diene)Cl)2(μ-7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)}