7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine

Base Information

Chemical Name:7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine
CAS No.:144101-82-6
Molecular Formula:C₂₂H₁₉N₂P
Molecular Weight:342.38
Hs Code.:
DSSTox Substance ID:DTXSID20578817
Wikidata:Q82469141
Mol file:144101-82-6.mol

Synonyms:144101-82-6;7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine;DTXSID20578817

Suppliers and Price of 7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine

Chemical Property:

XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:342.128585612
Heavy Atom Count:25
Complexity:398

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=NC2=C1C=CC(=N2)P(C3=CC=CC=C3)C4=CC=CC=C4)C

Technology Process of 7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine

There total 1 articles about 7-(Diphenylphosphanyl)-2,4-dimethyl-1,8-naphthyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77223-21-3
7-chloro-2,4-dimethyl-1,8-naphthyridine

: 829-85-6
diphenylphosphane

: 144101-82-6
7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1) hexane, THF, 15 min, 2) 4 h;
DOI:10.1039/DT9920002367

Reference yield: 100.0%

: 144611-99-4
{(Rh(C₈H₁₂)Cl)2(C₈H₃N₂(CH₃)2P(C₆H₅)2)}

: 144101-82-6
7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine

: 144611-98-3
{Rh(C₈H₁₂)(C₈H₃N₂(CH₃)2P(C₆H₅)2)Cl}

Guidance literature:: In dichloromethane; under N2: addn. of solid ligand to a soln. of Rh-complex in CH2Cl2, stirring for 30 min; addn. of hexane, pptn.; elem. anal.;
DOI:10.1039/DT9920002367

Reference yield: 95.0%

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 144101-82-6
7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine

: 155022-54-1
{(Ir(cycloocta-1,5-diene)Cl)2(μ-7-diphenylphosphino-2,4-dimethyl-1,8-naphthyridine)}

Guidance literature:: In dichloromethane; a mixt. of the phosphine and Ir complex was stirred in CH2Cl2 for 20 min; molar ratio of phosphine:Ir-complex = 1:1; N2 atm.;; pptn. by addn. of n-hexane; the ppt. was filtered off, washed with Et2O, and recrystd. from CH2Cl2/Et2O (1:1); elem. anal.;;
DOI:10.1016/0020-1693(93)03730-X