[Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

Base Information

Chemical Name:[Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]
CAS No.:363166-72-7
Molecular Formula:C₁₂H₂₀P*C₅₄H₇₅Cu₅P₃Te₆
Molecular Weight:2095.71
Hs Code.:

Synonyms:

Suppliers and Price of [Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

There total 1 articles about [Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

: 73296-31-8
phenyltellurotrimethylsilane

: copper(l) chloride

: 554-70-1
triethylphosphine

: 363166-72-7
[Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

: [Cu12Te3(μ3-TePh)6(PEt3)6]

Guidance literature:: In pentane; Irradiation (UV/VIS); under N2, standard Schlenk techniques; under visible light; PEt3 added to suspn. of CuCl (molar ratio 1:1) in pentane; stirred for 45 min; 1.2 equiv. of PhTeSiMe3 added; stirred for 1 h; crystd. overnight (Cu5 cluster obtained); crystals of Cu12 cluster obtained after a few more days; elem. anal.;
DOI:10.1021/ic001260k

Reference yield: 42.0%

: 363166-72-7
[Cu5(μ-TePh)3(μ3-TePh)3(PEt3)3][PEt3Ph]

: [Cu12Te3(μ3-TePh)6(PEt3)6]

: [Cu39(μ3-TePh)10(μ4-TePh)Te16(PEt3)13]

: [Cu29Te9(μ3-TePh)10(μ4-TePh)2(PEt3)8][PEt3Ph]

Guidance literature:: In tetrahydrofuran; byproducts: TePh2; Irradiation (UV/VIS); under N2, standard Schlenk techniques; Cu5 cluster and Cu12 cluster (molar ratio 1:1.4) dissolved in THF; stirred for 24 h under photolysis (320nm); layered with Et2O via slow diffusion; crystd. within a few d; solvent removed; washed with Et2O (Cu29 cluster obtained); crystals of Cu39 cluster obtained from mother liquor after 48-72 h; elem. anal.;
DOI:10.1021/ic001260k