tetraphenylarsonium tetracarbonyliridate

Base Information

• Chemical Name: tetraphenylarsonium tetracarbonyliridate
• CAS No.: 370858-28-9
• Molecular Formula: C₄IrO₄*C₂₄H₂₀As
• Molecular Weight: 687.606
• Mol file: 370858-28-9.mol

Synonyms:

Chemical Property of tetraphenylarsonium tetracarbonyliridate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylarsonium tetracarbonyliridate

There total 1 articles about tetraphenylarsonium tetracarbonyliridate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

tetrairidium dodecacarbonyl (18827-81-1) + carbon monoxide (201230-82-2) + tetraphenylarsonium chloride (507-28-8,14842-08-1) → tetraphenylarsonium tetracarbonyliridate (370858-28-9)

Guidance literature:

With Na-Hg; In tetrahydrofuran; water; Ir carbonyl was rduced with an excess of 0.75% sodium amalgam in THF with vigorous stirring under CO for 3 d; soln. was decanted off and added to a soln. of arsonium salt in water at 0°C; solid filtered off, carefully washed with water and dried in vacuo; recryst. from THF/Et2O; elem. anal.;

DOI:10.1021/ic0105011

upstream raw materials:

tetrairidium dodecacarbonyl

carbon monoxide

tetraphenylarsonium chloride