NanoKid

Base Information

Chemical Name:NanoKid
CAS No.:618904-86-2
Molecular Formula:C₃₉H₄₂O₂
Molecular Weight:542.761
Hs Code.:
UNII:Y83XMS9542
DSSTox Substance ID:DTXSID701019063
Nikkaji Number:J1.978.844J
Wikidata:Q56440487
Wikipedia:NanoPutian

Synonyms:NanoKid;Nanoputian;Y83XMS9542;UNII-Y83XMS9542;618904-86-2;1,3-Dioxolane, 2-(2,5-bis(3,3-dimethyl-1-butyn-1-yl)-4-(2-(3,5-di-1-pentyn-1-ylphenyl)ethynyl)phenyl)-;1,3-Dioxolane, 2-(2,5-bis(3,3-dimethyl-1-butynyl)-4-((3,5-di-1-pentynylphenyl)ethynyl)phenyl)-;2-(2,5-Bis(3,3-dimethyl-1-butyn-1-yl)-4-(2-(3,5-di-1-pentyn-1-ylphenyl)ethynyl)phenyl)-1,3-dioxolane;DTXSID701019063;Q56440487

Suppliers and Price of NanoKid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of NanoKid

Chemical Property:

XLogP3:10.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:11
Exact Mass:542.318480578
Heavy Atom Count:41
Complexity:1180

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCC#CC1=CC(=CC(=C1)C#CC2=CC(=C(C=C2C#CC(C)(C)C)C3OCCO3)C#CC(C)(C)C)C#CCCC

Technology Process of NanoKid

There total 13 articles about NanoKid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-37-6
1.4-dibromobenzene

: 618904-86-2
2-[2,5-bis-(3,3-dimethyl-but-1-ynyl)-4-(3,5-di-pent-1-ynyl-phenylethynyl)-phenyl]-[1,3]dioxolane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 81 percent / I₂; H₂SO₄ / 24 h / 125 - 135 °C

2.1: 70 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 20 h / 23 °C

3.1: n-BuLi / tetrahydrofuran / 1 h / -78 °C

3.2: 83 percent / tetrahydrofuran / 5 h / -78 - 20 °C

4.1: 77 percent / p-TsOH / toluene / 72 h / Heating

5.1: n-BuLi / tetrahydrofuran / 0.5 h / -78 °C

5.2: 86 percent / 1,2-diiodoethane / tetrahydrofuran / 20 °C

6.1: 85 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 25 - 50 °C

With copper(l) iodide; n-butyllithium; sulfuric acid; iodine; toluene-4-sulfonic acid; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; toluene;
DOI:10.1021/jo0349227

Reference yield:

: 6311-60-0
3,5-dibromonitrobenzene

: 618904-86-2
2-[2,5-bis-(3,3-dimethyl-but-1-ynyl)-4-(3,5-di-pent-1-ynyl-phenylethynyl)-phenyl]-[1,3]dioxolane

Guidance literature:: Multi-step reaction with 7 steps

1.1: 89 percent / SnCl₂*2H₂O / ethanol; tetrahydrofuran / 20 h / 20 °C

2.1: H₂SO₄; NaNO₂ / 2 h / 0 °C

2.2: 70 percent / KI / 0.25 h / 80 °C

3.1: 91 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 48 h / 20 °C

4.1: 2.86 g / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 75 - 80 °C

5.1: 0.84 g / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 72 h / 70 °C

6.1: 100 percent / K₂CO₃ / methanol; CH₂Cl₂ / 2 h / 23 °C

7.1: 85 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 25 - 50 °C

With copper(l) iodide; sulfuric acid; potassium carbonate; triethylamine; tin(ll) chloride; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; methanol; ethanol; dichloromethane; 2.2: Sandmeyer reaction;
DOI:10.1021/jo0349227

Reference yield:

: 626-40-4
3,5-dibromoaniline

: 618904-86-2
2-[2,5-bis-(3,3-dimethyl-but-1-ynyl)-4-(3,5-di-pent-1-ynyl-phenylethynyl)-phenyl]-[1,3]dioxolane

Guidance literature:: Multi-step reaction with 6 steps

1.1: H₂SO₄; NaNO₂ / 2 h / 0 °C

1.2: 70 percent / KI / 0.25 h / 80 °C

2.1: 91 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 48 h / 20 °C

3.1: 2.86 g / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 75 - 80 °C

4.1: 0.84 g / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 72 h / 70 °C

5.1: 100 percent / K₂CO₃ / methanol; CH₂Cl₂ / 2 h / 23 °C

6.1: 85 percent / CuI; Et₃N / (Ph₃P)2PdCl₂ / tetrahydrofuran / 25 - 50 °C

With copper(l) iodide; sulfuric acid; potassium carbonate; triethylamine; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; methanol; dichloromethane; 1.2: Sandmeyer reaction;
DOI:10.1021/jo0349227