3-methylthio-1,5-diphenylformazan

Base Information

• Chemical Name: 3-methylthio-1,5-diphenylformazan
• CAS No.: 89777-58-2
• Molecular Formula: C₁₄H₁₄N₄S
• Molecular Weight: 270.358
• Mol file: 89777-58-2.mol

Synonyms:

Chemical Property of 3-methylthio-1,5-diphenylformazan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-methylthio-1,5-diphenylformazan

There total 2 articles about 3-methylthio-1,5-diphenylformazan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{AgC13H11N4S} + methyl iodide (74-88-4) → 3-methylthio-1,5-diphenylformazan (6846-17-9,56677-22-6,89046-28-6,89777-57-1,89777-58-2) + silver(I) iodide

Guidance literature:

In chloroform; reflux for 1 h;

DOI:10.1039/JR9540004253 DOI:10.1038/169756a0

Reference yield:

→ 3-methylthio-1,5-diphenylformazan (6846-17-9,56677-22-6,89046-28-6,89777-57-1,89777-58-2)

Guidance literature:

aus Tetrazoliumjodid 12(R=Me,X=I) mit Na2S;

Reference yield:

bis(cyclopentadienyl)titanium dichloride (1271-19-8) + 3-methylthio-1,5-diphenylformazan (6846-17-9,56677-22-6,89046-28-6,89777-57-1,89777-58-2) → 2C5H5(1-)*Ti(4+)*C6H5NNC(SCH3)NNC6H5(1-)*Cl(1-) = (C5H5)2Ti(C6H5NNC(SCH3)NNC6H5)Cl

Guidance literature:

With triethylamine; In tetrahydrofuran; byproducts: Et3N*HCl; under strictly anhydrous conditions; S-methyl-1,5-di(phenyl)thiocarbazone and then triethylamine were added to a soln. of Cp2TiCl2 in THF (molar ratio 1:1:1); mixture was stirred for 42 h at room temp.; Et3N*HCl was removed by filtration; ppt. was crystd. from n-hexane/THF; elem. anal.;

upstream raw materials:

methyl iodide