((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6

Base Information

• Chemical Name: ((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6
• CAS No.: 126023-33-4
• Molecular Formula: C₃H₉P*C₅H₅*C₁₅H₁₆NO₃S*F₆P*Rh
• Molecular Weight: 679.406
• Mol file: 126023-33-4.mol

Synonyms:

Chemical Property of ((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6

There total 1 articles about ((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

silver(I) hexafluorophosphate (26042-63-7) + ((η5-cyclopentadienyl)iodo(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)trimethylphosphane)rhodium → ((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6 (126023-33-4)

Guidance literature:

In dichloromethane; byproducts: AgI; Under stirring a soln. of AgPF6 is added to a soln. of C5H5RhMe3P(I)CH2N(C6H4OMe)SO2(C6H4Me) at 25°C for 10 min (N2 or Ar), stirring for 10 min.; Ppt. is filtered off, filtrate is evapd. in vac.;

DOI:10.1016/0022-328X(89)85182-4

Reference yield: 58.0%

((η5-cyclopentadienyl)rhodium(N(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(trimethylphosphane))PF6 (126023-33-4) → ((η5-cyclopentadienyl)(N-(4-methoxyphenyl)(4-tolylsulfonyl)aminomethyl)(methoxy)(trimethylphosphane))rhodium

Guidance literature:

With potassium hydroxide; In methanol; Under stirring KOH is added to a soln. of Rh compd. at 0°C, mixt. is stirred for 5 min at 0°C, then soln. is allowed to warm to 25°C (N2 or Ar).; Solvent is removed in vac., residue is extd. with ether, ext. is evapd. to dryness, the yellow oil is dissolved in pentane, cooling to -78°C, ppt. is sepd. in the cold and dried in vac., elem. anal.;

DOI:10.1016/0022-328X(89)85182-4

upstream raw materials:

silver(I) hexafluorophosphate