Technology Process of C38H66O4Si3
There total 7 articles about C38H66O4Si3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 90 percent / DIBAL-H / CH2Cl2 / -78 - 20 °C
2.1: (COCl)2; DMSO; triethylamine / CH2Cl2 / -78 - 20 °C
2.2: MgBr2*OEt2 / CH2Cl2 / -60 °C
3.1: Et3N; DMAP / CH2Cl2 / 0 - 20 °C
4.1: Grubbs catalyst / CH2Cl2 / 144 h / 40 °C
5.1: LiBH4; CeCl3*7H2O / tetrahydrofuran; H2O / 20 °C
6.1: 2,6-lutidine / CH2Cl2 / 0 - 20 °C
With
2,6-dimethylpyridine; dmap; lithium borohydride; cerium(III) chloride; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine;
Grubbs catalyst first generation;
In
tetrahydrofuran; dichloromethane; water;
2.1: Swern oxidation;
DOI:10.1002/ejoc.200600760
- Guidance literature:
-
Multi-step reaction with 4 steps
1: Et3N; DMAP / CH2Cl2 / 0 - 20 °C
2: Grubbs catalyst / CH2Cl2 / 144 h / 40 °C
3: LiBH4; CeCl3*7H2O / tetrahydrofuran; H2O / 20 °C
4: 2,6-lutidine / CH2Cl2 / 0 - 20 °C
With
2,6-dimethylpyridine; dmap; lithium borohydride; cerium(III) chloride; triethylamine;
Grubbs catalyst first generation;
In
tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.200600760
- Guidance literature:
-
Multi-step reaction with 3 steps
1: Grubbs catalyst / CH2Cl2 / 144 h / 40 °C
2: LiBH4; CeCl3*7H2O / tetrahydrofuran; H2O / 20 °C
3: 2,6-lutidine / CH2Cl2 / 0 - 20 °C
With
2,6-dimethylpyridine; lithium borohydride; cerium(III) chloride;
Grubbs catalyst first generation;
In
tetrahydrofuran; dichloromethane; water;
DOI:10.1002/ejoc.200600760
