Technology Process of 4-methyl-1-(1-methyl-2-propenyl)-3-cyclohexen-1-ol
There total 1 articles about 4-methyl-1-(1-methyl-2-propenyl)-3-cyclohexen-1-ol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
iodine; magnesium;
Yield given. Multistep reaction;
1.) THF, 15 grad C, 2 h; 2.) heating, 1 h;
DOI:10.1016/S0040-4020(01)91487-5
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) BH3; 2.) 2 N NaOH, 30 percent H2O2, K2CO3 / 1.) THF, 0 grad C, 3 h; 2.) 1 h
2: 59 percent / pyridinium chlorochromate / CH2Cl2 / 2 h
3: 1.) 20 percent DIBAH; 2.) ice, acetic acid / 1.) toluene, -78 grad C, 3 h; 2.) 0 grad C
4: 1.) Mg, I2 / 1.) THF, 75 grad C, 1 h; 2.) THF, heating, 24 h
With
sodium hydroxide; Methamphetamin; borane; dihydrogen peroxide; iodine; diisobutylaluminium hydride; potassium carbonate; magnesium; acetic acid; pyridinium chlorochromate;
In
dichloromethane;
DOI:10.1016/S0040-4020(01)91487-5
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) BH3; 2.) 2 N NaOH, 30 percent H2O2, K2CO3 / 1.) THF, 0 grad C, 3 h; 2.) 1 h
2: 59 percent / pyridinium chlorochromate / CH2Cl2 / 2 h
3: 1.) 20 percent DIBAH; 2.) ice, acetic acid / 1.) toluene, -78 grad C, 3 h; 2.) 0 grad C
4: 1.) Mg, I2 / 1.) THF, 75 grad C, 1 h; 2.) THF, heating, 24 h
5: 39 percent / tosyl chloride / pyridine / 24 h / 0 - 25 °C
With
sodium hydroxide; Methamphetamin; borane; dihydrogen peroxide; iodine; diisobutylaluminium hydride; potassium carbonate; magnesium; acetic acid; p-toluenesulfonyl chloride; pyridinium chlorochromate;
In
pyridine; dichloromethane;
DOI:10.1016/S0040-4020(01)91487-5
