dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium

Base Information

• Chemical Name: dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium
• CAS No.: 31249-55-5
• Molecular Formula: C₁₄H₁₂Br₂N₂Pd
• Molecular Weight: 474.491
• Mol file: 31249-55-5.mol

Synonyms:

Chemical Property of dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium

There total 1 articles about dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

bis(acetonitrile)palladium(II) bromide (920282-22-0,53623-19-1) + 2.9-dimethyl-1,10-phenanthroline (484-11-7) + chloroform (67-66-3,8013-54-5) → dibromo(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')palladium (31249-55-5) + [Pd(II)(2,9-dimethyl-1,10-phenanthroline)2Br]Br*2H2O*CHCl3 + [Pd(II)(2,9-dimethyl-1,10-phenanthroline)2Br]2[Pd2Br6]*CHCl3 + palladium(II) bromide (13444-94-5)

Guidance literature:

In chloroform; under N2; suspn. was stirred at room temp. for 3 h, ppt. was isolated, reaction soln. was dried in vac., then CHCl3 soln. was placed in refrigerator at -20°C and few single crystals were formed over two days; elem. anal., XRD;

DOI:10.1039/c2dt11979j

upstream raw materials:

bis(acetonitrile)palladium(II) bromide

2.9-dimethyl-1,10-phenanthroline

chloroform