{Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

Base Information

Chemical Name:{Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂
CAS No.:139319-09-8
Molecular Formula:CH₂Cl₂*C₅₈H₆₀AuB₉P₃Rh
Molecular Weight:1332.14
Hs Code.:

{Rh(P(C<sub>6</sub>H<sub>5</sub>)3)2(H<sub>2</sub>)Au(P(C<sub>6</sub>H<sub>5</sub>)3)(C<sub>2</sub>B<sub>9</sub>H<sub>7</sub>(CH<sub>3</sub>)2)}*CH<sub>2</sub>Cl<sub>2</sub>

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Chemical Property of {Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

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Technology Process of {Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

There total 2 articles about {Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 14694-95-2
Wilkinson's catalyst

: {NEt₄}{10-endo-{Au(PPh₃)}-7,8-nido-C₂B₉H₉Me₂}

: 139319-09-8
{Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

Guidance literature:: With TlBF₄; CH₂Cl₂; In tetrahydrofuran; dissolving carborane, Rh complex and TlBF4 in THF; stirring at room temp. for 20 h under dry O2-free N2;; removal of solvent in vac.; suspending in CH2Cl2; filtration through Celite pad; reduction of volume in vac.; chromatography on alumina with CH2Cl2/hexane at -30°C; removal of solvent in vac.; crystn. from CH2Cl2/hexane; elem. anal.;;
DOI:10.1039/DT9930001073

Reference yield: 26.0%

: 35238-97-2
[(1,5-cyclooctadiene)Rh(PPh3)2]PF6

: {NEt₄}{10-endo-{Au(PPh₃)}-7,8-nido-C₂B₉H₉Me₂}

: C₅₈H₆₁Au₂B₉P₃Rh

: 139319-09-8
{Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

Guidance literature:: With H₂; In dichloromethane; dissolving carborane and Rh complex in CH2Cl2 under dry O2-free N2; cooling to -20°C; bubbling H2 through soln. for 3 h; warming to room temp. with H2 bubbling; change in color; stirring at room temp. for 24 h;; evapn. in vac.; dissolving in CH2Cl2; chromy. on alumina with CH2Cl2/hexane at -30°C; Au-complex: evapn. of red fraction and crystn. from CH2Cl2/hexane; Au2-complex: evapn. of yellow fraction in vac. and crystn. from CH2Cl2/hexane; elem. anal.;;
DOI:10.1039/DT9930001073

Reference yield:

: 139319-09-8
{Rh(P(C₆H₅)3)2(H₂)Au(P(C₆H₅)3)(C₂B₉H₇(CH₃)2)}*CH₂Cl₂

: 139319-05-4
Rh(P(C₆H₅)3)2(H)2AuP(C₆H₅)3C₂B₉H₇(CH₃)2

Guidance literature:: In dichloromethane; equil. in soln.;; not isolated; detected in soln. by (1)H, (13)C, (11)B and (31)P NMR spectroscopy;;
DOI:10.1039/DT9930001073