rac-1-(aminomethyl)-2-phenylferrocene

Base Information

Chemical Name:rac-1-(aminomethyl)-2-phenylferrocene
CAS No.:942472-60-8
Molecular Formula:C₁₇H₁₇FeN
Molecular Weight:291.176
Hs Code.:

Synonyms:rac-1-(aminomethyl)-2-phenylferrocene

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Chemical Property of rac-1-(aminomethyl)-2-phenylferrocene

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Technology Process of rac-1-(aminomethyl)-2-phenylferrocene

There total 1 articles about rac-1-(aminomethyl)-2-phenylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 79785-97-0
hydrazine hydrate

: 942472-59-5
rac-1-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl]-2-phenylferrocene

: 942472-60-8
rac-1-(aminomethyl)-2-phenylferrocene

Guidance literature:: In ethanol; byproducts: phthalazine-1,4-dione; (N2, Schlenk, a hood) to a suspn. of complex and hydrazine hydrate in ethanol was refluxed for 75 min at 95°C, cooled to room temp.; diethyl ether was added, the soln. was concd., dissolved in diethyl ether, washed twice with brine, dried (MgSO4), concd., flash chromy. (silicagel, hexanes/CH2Cl2 1:5+10% (C2H5)3N), as oil; elem. anal.;
DOI:10.1002/hlca.200790083

Reference yield: 96.0%

: 942472-60-8
rac-1-(aminomethyl)-2-phenylferrocene

: 7664-41-7
ammonia

: 942472-61-9
rac-1-(aminomethyl)-2-(cyclohexa-2,5-dienyl)ferrocene

Guidance literature:: With Li; In tetrahydrofuran; ethanol; (N2, Schlenk, a hood) to a freshly condensed liquid NH3 was canuled a precooled soln. of complex in ethanol and THF at -78°C, Li was added, stirred vigorously at -78°C for 1 h; quenched with NH4Cl, NH3 was evapd., the residue was poured into brine, aq. phase extd. twice with diethyl ether, dried overnight (Na2SO4), concd.; as oil;
DOI:10.1002/hlca.200790083