[Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl]

Base Information

• Chemical Name: [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl]
• CAS No.: 958877-41-3
• Molecular Formula: C₃₁H₂₈ClN₂PPd
• Molecular Weight: 601.423
• Mol file: 958877-41-3.mol

Synonyms:

Chemical Property of [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl]

There total 3 articles about [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

[Pd(8-diphenylphosphanylquinoline)(Me)Cl] (958877-23-1) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + 8-(diphenylphosphino)quinoline (28225-52-7) → [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl] (958877-41-3)

Guidance literature:

In dichloromethane; addn. dropwise of 2,6-dimethylphenyl isocyanide (1 equiv.) in CH2Cl2 under Ar to soln. of Pd(8-diphenylphosphanylquinoline)(Me)Cl (1 equiv.) and8-diphenylphosphanylquinoline in CH2Cl2; stirring for 1 h at room temp.; drying under reduced pressure; addn. of Et2O; filtration, washing with small aliquots of Et2O and with pentane; drying under vac. at room temp.;crystn., elem. anal.;

DOI:10.1021/om700555a

Reference yield:

[Pd(8-diphenylphosphanylquinoline)(Me)Cl] (958877-23-1) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl] (958877-41-3)

Guidance literature:

In dichloromethane; treatment of 2,6-dimethylphenyl isocyanide (1 equiv.) with Pd(8-diphenylphosphanylquinoline)(Me)Cl (1 equiv.) in CH2Cl2 at room temp.; monitoring by UV; Kinetics;

DOI:10.1021/om700555a

Reference yield:

[Pd(8-diphenylphosphanylquinoline)(Me)Cl] (958877-23-1) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + triethylbutylammonium chloride (24344-65-8) → [Pd(8-diphenylphosphanylquinoline)(1-(2,6-dimethylphenylimino)ethyl)Cl] (958877-41-3)

Guidance literature:

In dichloromethane; treatment of 2,6-dimethylphenyl isocyanide (1 equiv.) with Pd(8-diphenylphosphanylquinoline)(Me)Cl (1 equiv.) in CH2Cl2 in the presence of Et3BuNCl (10 equiv.) at room temp.; monitoring by UV; Kinetics;

DOI:10.1021/om700555a

upstream raw materials:

[Pd(8-diphenylphosphanylquinoline)(Me)Cl]

2,6-dimethylphenyl isonitrile

triethylbutylammonium chloride

8-(diphenylphosphino)quinoline