(η1-bis(diphenylphosphino)butane)tetracarbonylruthenium

Base Information

• Chemical Name: (η1-bis(diphenylphosphino)butane)tetracarbonylruthenium
• CAS No.: 297180-56-4
• Molecular Formula: C₃₂H₂₈O₄P₂Ru
• Molecular Weight: 639.589
• Mol file: 297180-56-4.mol

Synonyms:

Chemical Property of (η1-bis(diphenylphosphino)butane)tetracarbonylruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (η1-bis(diphenylphosphino)butane)tetracarbonylruthenium

There total 1 articles about (η1-bis(diphenylphosphino)butane)tetracarbonylruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 1,4-di(diphenylphosphino)-butane (7688-25-7) → (η1-bis(diphenylphosphino)butane)tetracarbonylruthenium (297180-56-4)

Guidance literature:

With C₂H₄; In n-heptane; Irradiation (UV/VIS); under N2; react. of an excess of phosphine ligand with Ru(CO)4(C2H4) generated by photolysis of an n-heptane soln. of Ru3(CO)12 under an atm ofethylene; not isolated, detected by NMR and IR;

DOI:10.1021/om000289t

Reference yield:

(η1-bis(diphenylphosphino)butane)tetracarbonylruthenium (297180-56-4) → (η2-bis(diphenylphosphino)butane)tricarbonylruthenium (297180-62-2)

Guidance literature:

In n-heptane; under N2; in temp. controlled infrared cell; rate constants were determined by monitoring IR absorbances at temp. from 322.58 K to 343.64 K; not isolated, detected by IR; Kinetics;

DOI:10.1021/om000289t

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

1,4-di(diphenylphosphino)-butane

Downstream raw materials:

(η2-bis(diphenylphosphino)butane)tricarbonylruthenium