(+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

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Chemical Name:(+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate
CAS No.:192824-91-2
Molecular Formula:C₄₉H₄₉O₃P₃Rh*F₆P
Molecular Weight:1026.72
Hs Code.:

(+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

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Chemical Property of (+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

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Technology Process of (+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

There total 1 articles about (+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 17084-13-8
potassium hexafluorophosphate

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 178674-52-7
(+/-)-(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)

: 192824-89-8,192824-91-2
(+/-)-[(2-(1-di(4-methylphenyl)phosphinyl-3-diphenylphosphinyl-2-propyloxy)-dibenzo[d,f]-1,3-dioxa-2-phosphepin)(η(4)-1,5-cyclooctadiene)rhodium(I)] hexafluorophosphate

Guidance literature:: In dichloromethane; acetone; byproducts: KCl; N2-atmosphere; stirring Rh-complex (in CH2Cl2) with 2 equiv. KPF6 (in Me2CO) for 5 min, addn. of 2 equiv. of ligand (in CH2Cl2), stirring for 20min; evapn. (vac.), dissoln. in CH2Cl2, drying (Na2SO4), centrifugation off of KCl, concn., pptn. on Et2O addn.; elem. anal.;
DOI:10.1016/S0022-328X(96)06930-6