Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Base Information

Chemical Name:Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane
CAS No.:891191-58-5
Molecular Formula:C₂₅H₂₃OSb
Molecular Weight:461.207
Hs Code.:

Synonyms:

Suppliers and Price of Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

There total 3 articles about Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 891753-17-6
[PdCl(Sb(R)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane)((S)-2-(1-(dimethylamino)ethyl)naphthyl))]*C₆H₆

: 891191-58-5,891191-64-3,891191-65-4
Sb(S)-(+)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Guidance literature:: With Ph₃P; In dichloromethane; (Ar); P compd. (1.1 equiv.) was added to soln. of Pd complex in CH2Cl2 at room temp.; mixt. was stirred for 10 min; concd. (vac.); chromd. (silica gel, hexane/CH2Cl2, 4/1);
DOI:10.1016/j.jorganchem.2005.10.042

Reference yield: 93.0%

: [PdCl(Sb(S)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane)((S)-2-(1-(dimethylamino)ethyl)naphthyl))]

: 891191-58-5,891191-64-3,891191-65-4
Sb(R)-(-)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Guidance literature:: With Ph₃P; In dichloromethane; (Ar); P compd. (1.1 equiv.) was added to soln. of Pd complex in CH2Cl2 at room temp.; mixt. was stirred for 10 min; concd. (vac.); chromd. (silica gel, hexane/CH2Cl2, 4/1);
DOI:10.1016/j.jorganchem.2005.10.042

Reference yield: 90.0%

: 312308-61-5
(phenylethynyl)(1-naphthyl)(p-tolyl)stibane

: 52711-30-5
1-bromo-2-(methoxymethyl)benzene

: 891191-65-4,891191-58-5,891191-64-3
(+/-)-(2-methoxymethylphenyl)(1-naphthyl)(4-tolyl)stibane

Guidance literature:: With n-BuLi; In diethyl ether; hexane; byproducts: LiCCPh; (Ar); soln. of BuLi in hexane and BrC6H4CH2OMe were reacted in ether at low temp.; Sb compd. was added with stirring over 50 min at -20°C; stirred at -20°C for 2 h; kept at room temp. for 1 h; dild. with ether and H2O; org. layer septd.; aq. layer extd. (ether); combined org. phase washed (brine); dried (MgSO4); evapd. (vac.); chromd. (silica gel, hexane/CH2Cl2, 4/1); recrystd. (hexane/C6H6); elem. anal.;
DOI:10.1016/j.jorganchem.2005.10.042