cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)]

Base Information

• Chemical Name: cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)]
• CAS No.: 212498-15-2
• Molecular Formula: C₃₂H₂₄ClF₅P₂Pt
• Molecular Weight: 796.015
• Mol file: 212498-15-2.mol

Synonyms:

Chemical Property of cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)]

There total 2 articles about cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

{platinum(II)(μ-chloride)(pentafluorophenyl)(tetrahydrothiophene)}2 + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)] (212498-15-2)

Guidance literature:

In chloroform; byproducts: C4H8S; (N2); Schlenk technique; P ligand (2 equiv.) was added to soln. of Pt complex in CHCl3 at room temp.; soln. was stirred for 2 h; concd.; treated with pentane; filtered; dried (vac.); elem. anal.;

DOI:10.1021/om060194c

Reference yield: 72.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + thallium(I) pentafluorobenzoate (68558-86-1) → cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)] (212498-15-2)

Guidance literature:

In pyridine; byproducts: TlCl, CO2; all manipulations under dry N2 atm.; Pt and Tl compds. (in molar ratio of 1:1) mixed with pyridine at various temps. (from room temp. to reflux)for various times; solvent removed in vac. at room temp., residue washed with hexane, extd.with acetone, filtered, evapd. to dryness,; elem. anal.;

DOI:10.1002/zaac.200400465

Reference yield: 83.1%

cis-[Pt(II)Cl(pentafluorophenyl)(1,2-bis(diphenylphosphino)ethane)] (212498-15-2) + water (7732-18-5) + silver trifluoromethanesulfonate (2923-28-6) → [Pt(H2O)(C6F5)(1,2-bis(diphenylphosphino)ethane)]O3SCF3 (894105-01-2)

Guidance literature:

In dichloromethane; acetone; byproducts: AgCl; (N2); Schlenk technique; soln. of Ag salt in acetone was added to soln. of Pt complex in wet CH2Cl2; suspn. was stirred for 3 h; filtered; concd.; treated with pentane; filtered; dried (vac.); elem. anal.;

DOI:10.1021/om060194c

upstream raw materials:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

thallium(I) pentafluorobenzoate

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

[Pt(H₂O)(C₆F₅)(1,2-bis(diphenylphosphino)ethane)]O₃SCF₃

[Pt(2,6-dimethylphenyl isocyanide)(C₆F₅)(1,2-bis(diphenylphosphino)ethane)]O₃SCF₃

Refernces

• 1、 Deacon, Glen B.,Elliott, Philip W.,Erven, Anja P.,Meyer, Gerd. "The synthesis by decarboxylation reactions and crystal structures of 1,n-bis(diphenylphosphino)alkane(pentafluorophenyl)-platinum(II) complexes". . p. 843 - 850. Retrieved 2008/10/09.