Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)-

Base Information

• Chemical Name: Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)-
• CAS No.: 67506-88-1
• Molecular Formula: C20H30 Cl2 Th
• Molecular Weight: 573.402

Synonyms:Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)-;Thorium dichlorobis[(1,2,3,4,5-.eta.)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-;Thorium dichlorobis[(1,2,3,4,5-.eta.5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-;67506-88-1

Chemical Property of Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 572.21051
• Heavy Atom Count: 23
• Complexity: 281

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[C-]1[C-]([C-]([C-]([C-]1C)C)C)C.C[C-]1C(=C(C(=C1C)C)C)C.Cl[Th]Cl

Technology Process of Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)-

There total 1 articles about Thorium dichlorobis((1,2,3,4,5-eta5)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + (C5Me5)2Th(IV)(η2-(O,C)-pyNO)(η2-(O,N)-ON=CH-(CH=CH)2-CH2Ph) → pyridine N-oxide (694-59-7) + bis(pentamethylcyclopentadienyl)thorium(IV) dichloride (67506-88-1)

Guidance literature:

In toluene; byproducts: HON=CH-(CH=CH)2-CH2Ph; complex reacted with HCl; NMR;

DOI:10.1039/b502439k

Reference yield: 90.0%

bis(pentamethylcyclopentadienyl)thorium(IV) dichloride (67506-88-1) + C12H20PSi(1-)*K(1+) → (C5Me5)2Th[P(mesityl)(SiMe3)]2 + (C5Me5)2Th(Cl)[P(mesityl)(SiMe3)]

Guidance literature:

In toluene; at 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.inorgchem.8b00922

Reference yield: 88.0%

bis(pentamethylcyclopentadienyl)thorium(IV) dichloride (67506-88-1) + 1-(2-cyclohexylethynyl)benzene (33414-83-4) → (η5-C5Me5)2Th[η2-C(Ph)C(C6H11)C(Ph)C(C6H11)]

Guidance literature:

With potassium graphite; In toluene; at 70 ℃; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00945

upstream raw materials:

hydrogenchloride

Downstream raw materials:

(C₅(CH₃)5)2Th(C₆H₄(CH₃))Cl

(C₅(CH₃)5)2Th(C₆H₄OCH₃)Cl

(C₅(CH₃)5)2Th(C₆H₄OCH₃)Br

((CCH₃)5)2ThCl(Si(C₆H₅)2(C(CH₃)3))

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 67506-88-1 Thorium,dichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]-

Send

Send

Metric Ton KG G Pound L ML

Send

Send