η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I)

Base Information

• Chemical Name: η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I)
• CAS No.: 169136-00-9
• Molecular Formula: C₁₇H₂₂IrNO₂S
• Molecular Weight: 496.653
• Mol file: 169136-00-9.mol

Synonyms:

Chemical Property of η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I)

There total 1 articles about η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + N-methyl-p-methoxybenzothiohydroxamic acid (209545-35-7) → η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I) (169136-00-9)

Guidance literature:

In N,N-dimethyl-formamide; stirring a mixt. of iridium complex and ligand in DMF for 2 min; addn. of water, centrifugation, dissolving in warm acetone, slow addn. of water, drying ppt. over P2O5 in vac. for 15 h;

DOI:10.1016/j.ica.2004.06.070

Reference yield:

η4-cycloocta-1,5-diene(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(I) (169136-00-9) + methyl iodide (74-88-4) → (η4-cycloocta-1,5-diene)iodomethyl(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(III) (852675-42-4)

Guidance literature:

In chloroform; react. iridium complex with CH3I at 25°C in chloroform; not isolated, detected by UV; Kinetics;

DOI:10.1016/j.ica.2004.06.070

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

N-methyl-p-methoxybenzothiohydroxamic acid

Downstream raw materials:

(η4-cycloocta-1,5-diene)iodomethyl(N-methyl-4-methoxybenzothiohydroxamato-κO,κS)iridium(III)