Pd(HOC₆H₄NCHC₆H₃NO₂)(HOC₆H₄NCHC₆H₃ON(CH₂CH₃)2)

Base Information

• Chemical Name: Pd(HOC₆H₄NCHC₆H₃NO₂)(HOC₆H₄NCHC₆H₃ON(CH₂CH₃)2)
• CAS No.: 690982-65-1
• Molecular Formula: C₃₀H₂₈N₄O₅Pd
• Molecular Weight: 630.996
• Mol file: 690982-65-1.mol

Synonyms:

Chemical Property of Pd(HOC₆H₄NCHC₆H₃NO₂)(HOC₆H₄NCHC₆H₃ON(CH₂CH₃)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd(HOC₆H₄NCHC₆H₃NO₂)(HOC₆H₄NCHC₆H₃ON(CH₂CH₃)2)

There total 2 articles about Pd(HOC₆H₄NCHC₆H₃NO₂)(HOC₆H₄NCHC₆H₃ON(CH₂CH₃)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

5-diethylamino-2-[[(4-hydroxyphenyl)imino]methyl]phenol (389612-74-2) + Pd2(OCOCH3)2(HOC6H4NCHC6H3NO2)2 (690982-60-6) → Pd(HOC6H4NCHC6H3NO2)(HOC6H4NCHC6H3ON(CH2CH3)2) (690982-65-1)

Guidance literature:

With sodium acetate; potassium carbonate; In ethanol; dichloromethane; dissolving ligand in ethanol/dichloromethane 1:3 mixt., addn. of sodium acetate and potassium carbonate, then palladium complex, stirring at room temp. for 2 h; filtration, concn.; elem. anal.;

DOI:10.1016/S0020-1693(03)00495-X

Reference yield:

4-{[(4-nitrophenyl)methylene]amino}phenol (129121-76-2,3230-42-0) → Pd(HOC6H4NCHC6H3NO2)(HOC6H4NCHC6H3ON(CH2CH3)2) (690982-65-1)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid

2: sodium acetate; potassium carbonate / dichloromethane; ethanol

With sodium acetate; potassium carbonate; In ethanol; dichloromethane; acetic acid;

DOI:10.1016/S0020-1693(03)00495-X

Reference yield: 61.0%

Pd(HOC6H4NCHC6H3NO2)(HOC6H4NCHC6H3ON(CH2CH3)2) (690982-65-1) + pentyloxyterephthalic acid chloride → Pd(2+)*NO2C6H3CHNC6H4OCOC6H3OC5H11COOC6H4NCHC6H3ON(CH2CH3)2(2-)=PdNO2C6H3CHNC6H4OCOC6H3OC5H11COOC6H4NCHC6H3ON(CH2CH3)2

Guidance literature:

With KOH; tetrabutylammonium hydrogen sulfate; In chloroform; water; dispersing palladium complex in water with KOH and ammonium salt, addn. of a soln. of acyl chloride in CHCl3, stirring for 8 min; addn. of heptane, filtration, washing with water, ethanol, CHCl3/pentane1:2, ethanol with sodium acetate, water, ethanol, dissolving in 1,1,2,2 -tetrachloroethane, addn. of heptane, filtration, washing with hexane, drying at 80°C; elem. anal.;

DOI:10.1016/S0020-1693(03)00495-X

upstream raw materials:

5-diethylamino-2-[[(4-hydroxyphenyl)imino]methyl]phenol

Pd₂(OCOCH₃)2(HOC₆H₄NCHC₆H₃NO₂)2

4-{[(4-nitrophenyl)methylene]amino}phenol