Al(CH₃)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C₆H₅CH₃

Base Information

• Chemical Name: Al(CH₃)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C₆H₅CH₃
• CAS No.: 548476-04-6
• Molecular Formula: C₇H₈*C₆₂H₄₈AlNO₂Si₂
• Molecular Weight: 1014.36
• Mol file: 548476-04-6.mol

Synonyms:

Chemical Property of Al(CH₃)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C₆H₅CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Al(CH₃)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C₆H₅CH₃

There total 1 articles about Al(CH₃)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C₆H₅CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

pyridine (110-86-1) + trimethylaluminium dimer + (S)-3,3'-bis(triphenylsilyl)-2,2'-dihydroxy-1,1'-dinaphthyl (111795-33-6,111822-69-6,126911-86-2) + toluene (108-88-3,15644-74-3,16713-13-6) → AlMe3(pyridine) (6125-66-2) + Al(CH3)(py)((S)-3,3'-bis(triphenylsilyl)-1,1'-bi-2,2'-naphthoxide))*C6H5CH3 (548476-04-6)

Guidance literature:

In toluene; benzene; using Schlenk techniques; to flask contg. benzene added soln. of AlMe3 in toluene; org. ligand dissolved in benzene slowly added to stirred mixt.; pyridine added; mixt. stirred for 17 h; evapd. to dryness; dissolved in toluene; layered with hexane; crystals were obtained; elem. anal.;

DOI:10.1021/om030011b

upstream raw materials:

pyridine

(S)-3,3'-bis(triphenylsilyl)-2,2'-dihydroxy-1,1'-dinaphthyl

toluene