[2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone

Base Information

• Chemical Name: [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone
• CAS No.: 75465-10-0
• Molecular Formula: C₁₆H₂₀O
• Molecular Weight: 228.334
• Mol file: 75465-10-0.mol

Synonyms:

Chemical Property of [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone

There total 2 articles about [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chrysanthemumic acid methyl ester (5460-63-9) → [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone (75465-10-0,75465-11-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dimethylaluminum chloride / dichloromethane; n-heptane / 1 h / 0 - 20 °C / Inert atmosphere

1.2: 12 h / 20 °C / Inert atmosphere

2.1: tetrahydrofuran; diethyl ether / 3 h / 0 °C / Inert atmosphere

With dimethylaluminum chloride; In tetrahydrofuran; diethyl ether; n-heptane; dichloromethane;

DOI:10.1039/c9nj03210j

Reference yield:

C12H21NO2 + phenylmagnesium bromide (100-58-3) → [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone (75465-10-0,75465-11-1)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 0 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c9nj03210j

Reference yield:

dimethylsulfide (75-18-3) + [2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone (75465-10-0,75465-11-1) → C13H14O2

Guidance literature:

[2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropyl]-phenyl-methanone; With ozone; In dichloromethane; at -78 ℃; Inert atmosphere;

dimethylsulfide; In dichloromethane; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1039/c9nj03210j

upstream raw materials:

phenylmagnesium bromide

chrysanthemumic acid methyl ester