cis-{Pt(PPh₃)2Cl(nitrate)}

Base Information

• Chemical Name: cis-{Pt(PPh₃)2Cl(nitrate)}
• CAS No.: 1140480-99-4
• Molecular Formula: C₃₆H₃₀ClNO₃P₂Pt
• Molecular Weight: 817.12
• Mol file: 1140480-99-4.mol

Synonyms:

Chemical Property of cis-{Pt(PPh₃)2Cl(nitrate)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-{Pt(PPh₃)2Cl(nitrate)}

There total 5 articles about cis-{Pt(PPh₃)2Cl(nitrate)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) + cis-[bis(triphenylphosphane)bis(nitrato)platinul(II)] (1140481-03-3,16009-24-8,17611-57-3) → cis-{Pt(PPh3)2Cl(nitrate)} (1140480-99-4,64024-03-9,33915-20-7)

Guidance literature:

In dichloromethane; stirred for 1 h, allowed to stand for 1 night; slow diffusion of diethyl ether into the CH2Cl2 soln., filtered off, washed with diethyl ether, dried (vac., room temp.); elem. anal.;

DOI:10.1016/S0020-1693(00)85170-1

Reference yield:

cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) → cis-{Pt(PPh3)2Cl(nitrate)} (1140480-99-4,64024-03-9,33915-20-7)

Guidance literature:

With silver nitrate; In methanol; dichloromethane; byproducts: AgCl; addn. of AgNO3 in MeOH within 30 min to a stirred soln. of cis-(Pt(PPh3)2Cl2) in CH2Cl2; evapn. to dryness (reduced pressure, room temp.), removal of AgCl (addn. of CH2Cl2, filtration), volume of filtrate reduced, slow diffusion of diethyl ether in the soln., filtered off, washed with diethyl ether, dried at room temp. in vac.;

DOI:10.1016/S0020-1693(00)85170-1

Reference yield:

{Pt(1,5-cyclooctadiene)Cl(nitrate)} (123247-11-0) → cis-{Pt(PPh3)2Cl(nitrate)} (1140480-99-4,64024-03-9,33915-20-7)

Guidance literature:

With triphenylphosphine; In dichloromethane; addn. of PPh3 in 30 min; slow diffusion of diethyl ether in the CH2Cl2 soln., filtered off, washed with diethyl ether, dried (vac., 70°C);

DOI:10.1016/S0020-1693(00)85170-1

upstream raw materials:

cis-dichlorobis(triphenylphosphine)platinum(II)

cis-[bis(triphenylphosphane)bis(nitrato)platinul(II)]

{Pt(1,5-cyclooctadiene)Cl(nitrate)}

{Pt(P(C₆H₅)3)3Cl}⁽¹⁺⁾*NO₃^(1-)={Pt(P(C₆H₅)3)3Cl}(NO₃)

Downstream raw materials:

cis-[bis(triphenylphosphane)bis(nitrato)platinul(II)]

{Pt(P(C₆H₅)3)3(NO₃)}⁽¹⁺⁾*NO₃^(1-)={Pt(P(C₆H₅)3)3(NO₃)}(NO₃)

{Pt(P(C₆H₅)3)3Cl}⁽¹⁺⁾*NO₃^(1-)={Pt(P(C₆H₅)3)3Cl}(NO₃)