3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8⁽¹⁾,9,11-triene

Base Information

• Chemical Name: 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8⁽¹⁾,9,11-triene
• CAS No.: 95891-62-6
• Molecular Formula: C₃₃H₁₉Fe₃O₉P₃
• Molecular Weight: 819.971

Synonyms:

Chemical Property of 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8⁽¹⁾,9,11-triene

Chemical Property:

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Safty Information:

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MSDS Files:

Useful:

Technology Process of 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8⁽¹⁾,9,11-triene

There total 5 articles about 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8⁽¹⁾,9,11-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

(C6H4(PC6H5)3)Fe3(CO)9 → 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8(1),9,11-triene (95891-62-6)

Guidance literature:

In benzene; under N2 or Ar, treated at 80.5°C for 76 min, various yields forvarious conditions; HPLC; Kinetics;

Reference yield: 8.0%

diiron nonacarbonyl (15321-51-4) + 1,2,3-triphenyl-1,2,3-triphosphaindane (89104-79-0,57194-41-9,5994-68-3) → [4,4,4,5,5,5-hexacarbonyl-2,3,6-triphenyl-2,3,6-triphospha-4,5-diferratetracyclo[5.4.0.0(3,5).0(4,6).]undeca7(1),8,10-triene]tetracarbonyliron (89210-02-6) + 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8(1),9,11-triene (95891-62-6) + (C6H4(PC6H5)3)(Fe(CO)4)2 (57139-05-6) + (C6H4(PC6H5)2)Fe2(CO)6 + (C6H4(PC6H5)3)Fe3(CO)9

Guidance literature:

In benzene; under N2 or Ar, Fe-compd. added in one portion to soln. of P-compd. at 70°C, refluxed for 0.5 h, various yields for various conditions; cooled, chromy. on silica gel with hexane/ethyl acetate, concd., preparative HPLC on silica gel with hexane/ethyl acetate, recrystd., elem. anal.;

Reference yield: 3.0%

diiron nonacarbonyl (15321-51-4) + 1,2,3-triphenyl-1,2,3-triphosphaindane (89104-79-0,57194-41-9,5994-68-3) → 3,3,3,4,4,4,6,6,6-nonacarbonyl-2,5,7-triphenyl-2,5,7-triphospha-3,4,6-triferrapentacyclo[6.4.0.0(2,6).0(3,5).0(4,7).]dodeca-8(1),9,11-triene (95891-62-6)

Guidance literature:

In benzene; under N2 or Ar, Fe-compd. added in one portion to soln. of P-compd. at 70°C, refluxed for 15 h; cooled, chromy. on silica gel with hexane/ethyl acetate, concd., preparative HPLC on alumina with CH2Cl2/hexane, recrystd. from hexane/ethyl acetate, mass spectrum, elem. anal.;

upstream raw materials:

triiron dodecarbonyl

1,2,3-triphenyl-1,2,3-triphosphaindane

diiron nonacarbonyl

[4,4,4,5,5,5-hexacarbonyl-2,3,6-triphenyl-2,3,6-triphospha-4,5-diferratetracyclo[5.4.0.0(3,5).0(4,6).]undeca7⁽¹⁾,8,10-triene]tetracarbonyliron

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