mer-{ReOCl₃(dppm-P,P')}

Base Information

Chemical Name:mer-{ReOCl₃(dppm-P,P')}
CAS No.:136087-93-9
Molecular Formula:C₂₅H₂₂Cl₃OP₂Re
Molecular Weight:692.963
Hs Code.:

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Chemical Property of mer-{ReOCl₃(dppm-P,P')}

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Technology Process of mer-{ReOCl₃(dppm-P,P')}

There total 6 articles about mer-{ReOCl₃(dppm-P,P')} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 14853-14-6
tetraphenylarsonium tetrachlorooxorhenate(V)

: 2071-20-7
bis-diphenylphosphinomethane

: 136087-93-9,148497-40-9,60260-17-5
fac-{ReOCl₃(dppm-P,P')}

Guidance literature:: In chloroform; dissolving a stoichiometric amt. of ((C6H5)2P)2CH2 (0.18mmol)in degassed CHCl3 (30ml);dropwise addn. to a refluxing soln. of (As(C6H5)4)(ReOCl4)in CHCl3 (30ml) purged with Ar, 10min; color change from yellow to green blue in a few min; slow pptn.;; filtration after 20min; washing with ethanol and diethyl ether; recrystg. from hot CH2Cl2-CH3NO2; elem. anal.;;
DOI:10.1016/S0020-1693(00)88114-1

Reference yield: 85.0%

: [ReOCl₃(PPh₃)₂]

: 2071-20-7
bis-diphenylphosphinomethane

: 136087-93-9,148497-40-9,60260-17-5
fac-{ReOCl₃(dppm-P,P')}

Guidance literature:: In chloroform; dissolving a stoich. amt. of ((C6H5)2P)2CH2 (0.18mmol)in degassed CHCl3 (30ml);dropwise addn. to a refluxing soln. of (ReOCl3(P(C6H5)3)2) (0.18mmol)in CHCl3 (30ml) purged with Ar, 10min; color change from yellow to green blue in a few min; slow pptn.;; filtration after 20min; washing with ethanol and diethyl ether; recrystg. from hot CH2Cl2-CH3NO2; elem. anal.;;
DOI:10.1016/S0020-1693(00)88114-1

Reference yield: 81.0%

: 87863-04-5,608133-96-6
ReOCl3(triphenylarsine)2

: 2071-20-7
bis-diphenylphosphinomethane

: 136087-93-9,148497-40-9,60260-17-5
fac-{ReOCl₃(dppm-P,P')}

Guidance literature:: In dichloromethane; stirred under nitrogen for 40 min, volume reduced in vac.; standing at -20°C for 4 h, filtered, washing with CH2Cl2, elem. anal.;
DOI:10.1039/DT9910001519