[((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)]

Base Information

• Chemical Name: [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)]
• CAS No.: 1144033-43-1
• Molecular Formula: C₃₆H₂₈AuFe₂P
• Molecular Weight: 800.253
• Mol file: 1144033-43-1.mol

Synonyms:

Chemical Property of [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)]

There total 1 articles about [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

ferroceneacetylene (1271-47-2) + [((diphenyl)ferrocene-ethynyl phosphine)AuCl] (1144033-41-9) → [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)] (1144033-43-1)

Guidance literature:

copper(l) iodide; In diethylamine; (N2); using Schlenk techniques; addn. of (CuI) to diethylamine soln. containing of (ferrocene-ethynyl)Ph2PAuCl and ethynylferrocene; stirring for 2 h at 25°C; removal of all volatiles in vac., chromy. on silica gel with hexane/Et2Omixt. (1:4, vs/vs) as eluent; elem. anal.;

DOI:10.1016/j.jorganchem.2008.11.046

Reference yield:

[((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)] (1144033-43-1) → [((diphenyl)ferrocene-ethynyl phosphine)Au(ferrocene-ethynyl)](2+)

Guidance literature:

With (N-C₄H₉)4NPF₆; In 1,2-dichloro-ethane; Electrolysis; dissolving of ((ferrocene-ethynyl)Ph2P)Au(ferrocene ethynyl) in 1,2-dichloroethane in the presence of ((n-C4H9)4N)PF6; placing in optically transparent thin-layer electrolysis cell; monitoring by UV/Vis/NIR;

DOI:10.1016/j.jorganchem.2008.11.046

upstream raw materials:

ferroceneacetylene

[((diphenyl)ferrocene-ethynyl phosphine)AuCl]