[(η5-Ph2P(O)C5H4)2Co]PF6

Base Information

• Chemical Name: [(η5-Ph2P(O)C5H4)2Co]PF6
• CAS No.: 761405-20-3
• Molecular Formula: C₃₄H₂₈CoO₂P₂*F₆P
• Molecular Weight: 734.5
• Mol file: 761405-20-3.mol

Synonyms:

Chemical Property of [(η5-Ph2P(O)C5H4)2Co]PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(η5-Ph2P(O)C5H4)2Co]PF6

There total 2 articles about [(η5-Ph2P(O)C5H4)2Co]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1,1'-bis(diphenylphosphino)cobaltocenium hexafluorophosphate (67292-48-2) + dihydrogen peroxide (7722-84-1) → [(η5-Ph2P(O)C5H4)2Co]PF6 (761405-20-3)

Guidance literature:

In tetrahydrofuran; water; cobaltocene deriv. in THF cooled to 0°C, aq. H2O2, soln. allowed to stir at ambient temp. for 1.5 h; solvent removed in vacuo, residue dissolved in CH2Cl2, dried over Na2SO4, filtered via cannula; solvent removed in vacuo; residue washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1016/j.jorganchem.2011.09.004

Reference yield:

peracetic acid (79-21-0) + 1,1'-bis(diphenylphosphino)cobaltocenium hexafluorophosphate (67292-48-2) → [(η5-Ph2P(O)C5H4)2Co]PF6 (761405-20-3)

Guidance literature:

In water; acetone; (N2); standard Schlenk technique; aq. peracetic acid was added to soln. of Co complex in acetone; mixt. was stirred at room temp. for 2 h; solvent removed (vac.); H2O and CH2Cl2 added; mixt. thoroughly stirred; CH2Cl2 phase septd.; dried (Na2SO4); evapd.; redissolved in CH2Cl2; hexane carefully layered overnight; elem. anal.;

DOI:10.1021/om049667a

upstream raw materials:

peracetic acid

1,1'-bis(diphenylphosphino)cobaltocenium hexafluorophosphate

dihydrogen peroxide