2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

Base Information

Chemical Name:2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide
CAS No.:500783-42-6
Molecular Formula:C₄₄H₇₀N₄O₇Si₃
Molecular Weight:851.319
Hs Code.:

2-azido-3-benzyloxy-6-(<i>tert</i>-butyl-dimethyl-silanyloxy)-2-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

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Chemical Property of 2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

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Technology Process of 2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

There total 1 articles about 2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 344615-50-5
(2S,3R,4R,5S)-N,N-dimethyl-2-azido-3-benzyloxy-6-(tert-butyldimethylsilyloxy)-2-(tert-butyldiphenylsilyloxymethyl)-4-(p-methoxybenzyloxy)-5-[2-(trimethylsilyl)ethoxymethoxy]hexanoamide

: 500783-42-6
2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 0 ℃; for 3h;
DOI:10.1016/S0040-4039(01)00246-5

Reference yield:

: 500783-42-6
2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

: 344615-51-6
(1'S,3S,4R,5S)-3-azido-4-benzyloxy-5-[2'-(tert-butyldimethylsilyloxy)-1'-[2-(trimethylsilyl)ethoxymethoxy]ethyl]-3-(tert-butyldiphenylsilyloxymethyl)-2-oxo-tetrahydrofuran

Guidance literature:: With pyridinium p-toluenesulfonate; In toluene; at 70 ℃; for 24h;
DOI:10.1016/S0040-4039(01)00246-5

Reference yield:

: 500783-42-6
2-azido-3-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-5-(2-trimethylsilanyl-ethoxymethoxy)-hexanoic acid dimethylamide

: (3S,4R,5S)-3-Amino-5-[(S)-2-(tert-butyl-dimethyl-silanyloxy)-1-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-3-(tert-butyl-diphenyl-silanyloxymethyl)-4-hydroxy-dihydro-furan-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: PPTS / toluene / 24 h / 70 °C

2: 61 percent / NaBrO₃; NaHSO₃ / H₂O; ethyl acetate / 1 h / 20 °C

3: H₂ / Pd/C / ethyl acetate / 14 h / 20 °C

With sodium bromate; hydrogen; pyridinium p-toluenesulfonate; sodium hydrogensulfite; palladium on activated charcoal; In water; ethyl acetate; toluene;
DOI:10.1016/S0040-4039(01)00246-5