(η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl

Base Information

• Chemical Name: (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl
• CAS No.: 579504-99-7
• Molecular Formula: C₃₃H₂₇ClNNiP
• Molecular Weight: 562.701
• Mol file: 579504-99-7.mol

Synonyms:

Chemical Property of (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl

There total 1 articles about (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + 2-(3-indenylmethyl)pyridine (378797-57-0) → (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl (579504-99-7)

Guidance literature:

With BuLi; In diethyl ether; under N2; Et2O soln. of ligand and soln. of BuLi in hexane stirred at room temp. for 4 h; transferred dropwise over 1.5 h to stirred slurry of Ni complex in Et2O; filtered; filtrate vol. reduced; ppt. collected; elem. anal.;

DOI:10.1021/om030241q

Reference yield: 58.0%

(η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl (579504-99-7) + sodium tetraphenyl borate (143-66-8) → [(η3:η1-2-(1-indenylmethyl)pyridine)nickel(PPh3)][BPh4] (579505-04-7)

Guidance literature:

In dichloromethane; under N2; CH2Cl2 soln. of Ni complex and NaBPh4 stirred for 24 h; filtered; filtrate vol. reduced; pptd. by adding Et2O; powder isolated after repeated pptn.; elem. anal.;

DOI:10.1021/om030241q

Reference yield:

(η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl (579504-99-7) → [(η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)2](1+)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane-d2

In dichloromethane; dichloromethane-d2;

DOI:10.1021/om030241q

upstream raw materials:

bis(triphenylphosphine)nickel(II) chloride

2-(3-indenylmethyl)pyridine

Downstream raw materials:

[(η3:η1-2-(1-indenylmethyl)pyridine)nickel(PPh3)](1+)

[(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl]

(η3:η0-N-(1-indenylethyl)pyrolidine)nickel(PPh3)Cl

[(η3:η1-2-(1-indenylmethyl)pyridine)nickel(PPh3)][BPh4]