(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl

Base Information

• Chemical Name: (η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl
• CAS No.: 267901-88-2
• Molecular Formula: C₃₁H₃₁ClNNiP
• Molecular Weight: 542.711
• Mol file: 267901-88-2.mol

Synonyms:

Chemical Property of (η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl

There total 2 articles about (η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + 3-(2-(N,N-dimethylamino)ethyl)indene (14780-23-5) → [(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl] (267901-88-2)

Guidance literature:

With BuLi; In diethyl ether; hexane; byproducts: PPh3, Ph3PO; The mixt. of the indene and BuLi (hexane) in Et2O was stirred for 30 min at room temp., then transferred dropwise to the stirred suspn. of complex in Et2O (N2 atm.);; filtered, evapd., extd. with hexane, concd., cooled, recrystd. from Et2O/hexane and cyclohexane/hexane; elem. anal.;;

DOI:10.1021/om9907122

Reference yield:

[(η3:η1-N-(1-indenylethyl)dimethylamine)nickel(PPh3)](1+) (267901-90-6) + (η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl (579504-99-7) → [(η3:η1-2-(1-indenylmethyl)pyridine)nickel(PPh3)](1+) (579505-03-6) + [(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl] (267901-88-2)

Guidance literature:

In not given; under N2;

DOI:10.1021/om030241q

Reference yield: 93.0%

(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Cl (267901-88-2) + tricyclohexylphosphine (2622-14-2) → (η3:η0-Ind(CH2)2NMe2)Ni(PCy3)Cl*H2O

Guidance literature:

In diethyl ether; under N2 atm. (Ind(CH2)NMe2)Ni(PPh3)Cl and PCy3 were mixed in Et2O and stirred for 3 h; soln. was concd. and cooled to -20°C; elem. anal.;

DOI:10.1021/om0341348

upstream raw materials:

bis(triphenylphosphine)nickel(II) chloride

3-(2-(N,N-dimethylamino)ethyl)indene

[(η3:η1-N-(1-indenylethyl)dimethylamine)nickel(PPh3)](1+)

(η3:η0-2-(1-indenylmethyl)pyridine)nickel(PPh3)Cl

Downstream raw materials:

C₉H₆(CH₂)2N(CH₃)2Ni(P(C₆H₅)3)2⁽¹⁺⁾

[(η3:η1-Ind(CH2)2NMe2)Ni(PPh3)][BPh4]

(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)Me

[(η3:η0-Ind(CH2)2NMe2)Ni(PPh3)(PMe3)][BPh4]