[(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph]

Base Information

• Chemical Name: [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph]
• CAS No.: 1244977-97-6
• Molecular Formula: C₂₅H₃₈BFeNOSi₂
• Molecular Weight: 491.412
• Mol file: 1244977-97-6.mol

Synonyms:

Chemical Property of [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph]

There total 1 articles about [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

[(η5-C5Me5)(OC)2Fe(μ-BN(SiMe3)2C=C)Ph] → [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph] (1244977-97-6)

Guidance literature:

In benzene-d6; Irradiation (UV/VIS); (Ar) soln. Fe complex in C6D6 was irradiated with Hg/Xe arc lamp (400-550W) equipped with IR filterr (210-600 nm) for 4 h at room temp.; volatiles were removed in vacuo, residue was extd. with hexane, concd. and stored at -30°C for several days; elem. anal.;

DOI:10.1021/ic1010874

Reference yield: 65.0%

[(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph] (1244977-97-6) + trimethylphosphane (594-09-2) → [(η5-C5Me5)(OC)(PMe3)Fe(μ-BN(SiMe3)2C=C)Ph]

Guidance literature:

In hexane; (Ar) soln. Fe complex and PMe3 in hexane was heated in oil bath at 80°C for 1 h; volatiles were removed in vacuo, residue was extd. with hexane and stored at -70°C for several weeks; elem. anal.;

DOI:10.1021/ic1010874

Reference yield: 52.0%

carbon monoxide (201230-82-2) + [(η5-C5Me5)(OC)FeBN(SiMe3)2(η2-CC)Ph] (1244977-97-6) → [(η5-C5Me5)(OC)2FeBN(SiMe3)2CCPh] (1244977-98-7)

Guidance literature:

In benzene-d6; CO atm., 2 h; volatiles were removed in vacuo, residue was extd. with hexane and stored at -70°C for a few days; elem. anal.;

DOI:10.1021/ic1010874

Downstream raw materials:

[(η5-C5Me5)(OC)2FeBN(SiMe3)2CCPh]