(R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane

Base Information

Chemical Name:(R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane
CAS No.:139506-07-3
Molecular Formula:C₁₀H₂₀O₆S₂
Molecular Weight:300.397
Hs Code.:
European Community (EC) Number:604-143-5
NSC Number:76458
DSSTox Substance ID:DTXSID70291564
Nikkaji Number:J1.445.417I
Wikidata:Q72446144

Synonyms:186204-35-3;(R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane;(R,R)-1,2-Bis(methanesulfonyloxymethyl)cyclohexane;(1R,2R)-1,2-Bis(methanesulfonyloxymethyl)cyclohexane;[(1R,2R)-2-(methylsulfonyloxymethyl)cyclohexyl]methyl methanesulfonate;(1R,2R)-1,2-Bis[[(methylsulfonyl)oxy]methyl]cyclohexane;139506-07-3;MFCD12923309;NSC76458;SCHEMBL924034;(1R,2R)-1,2-Cyclohexanedimethanol 1,2-Dimethanesulfonate;DTXSID70291564;AMY32497;NSC-76458;AKOS015999600;CS-O-31311;AC-24376;DS-16691;CS-0031399;trans-1,2-bis(methanesulfonyloxymethyl)cyclohexane;A1-00283;J-502303;(R,R)-1,2-Bis(Methanesulfonyloxymethyl)-cyclohexane;(R,R)-trans-1,2-Bis(methanesulfonyloxymethyl)cyclohexane;[(1R,2R)-Cyclohexane-1,2-diyl]bis(methylene) dimethanesulfonate;[(1R,2R)-2-[(methanesulfonyloxy)methyl]cyclohexyl]methyl methanesulfonate;Bis(methanesulfonic acid)[(1R,2R)-1,2-cyclohexanediyl]bismethylene ester

Suppliers and Price of (R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of (R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane

Chemical Property:

XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:300.07013070
Heavy Atom Count:18
Complexity:398

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CS(=O)(=O)OCC1CCCCC1COS(=O)(=O)C
Isomeric SMILES:CS(=O)(=O)OC[C@@H]1CCCC[C@H]1COS(=O)(=O)C

Technology Process of (R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane

There total 3 articles about (R,R)-1,2-Bis(Methanesulphonyloxymethyl)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 76155-27-6,25712-33-8
(+/-)-trans-2-(hydroxymethyl)cyclohexylmethanol

: 124-63-0
methanesulfonyl chloride

: 66347-68-0,139506-07-3
(±)-(1S, 2S)-cyclohexane-1,2-dimethanol bis(methanesulfonate)

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃; for 2h;
DOI:10.1021/ml400235c

Reference yield:

: 3205-35-4
trans dimethyl cyclohexane-1,2-dicarboxylate

: 66347-68-0,139506-07-3
(±)-(1S, 2S)-cyclohexane-1,2-dimethanol bis(methanesulfonate)

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄; diethyl ether

2: pyridine

With pyridine; lithium aluminium tetrahydride; diethyl ether;
DOI:10.1039/jr9530000399