3-exo-hydroxynorcamphor

Base Information

• Chemical Name: 3-exo-hydroxynorcamphor
• CAS No.: 119565-95-6
• Molecular Formula: C₇H₁₀O₂
• Molecular Weight: 126.155
• Mol file: 119565-95-6.mol

Synonyms:

Chemical Property of 3-exo-hydroxynorcamphor

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-exo-hydroxynorcamphor

There total 1 articles about 3-exo-hydroxynorcamphor which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

2-diazonorbornan-3-one (5169-59-5) → 1,2,5,6-tetrahydrobenzoic acid (4771-80-6) + 2-endo-hydroxynorbornan-3-one (5164-67-0,5164-68-1,89898-01-1,119565-95-6) + 2-hydroxybicyclo<3.1.1>heptan-6-one (5597-91-1,41780-95-4) + tricyclo<2.2.1.02.6>heptanone (695-05-6)

Guidance literature:

With sulfuric acid; In water;

Reference yield:

endo-2-hydroxybicyclo<2.2.1>heptan-3-one (5164-67-0,5164-68-1,89898-01-1,119565-95-6) → Cyclohex-3-enecarboxylic acid 2,2,2-trifluoro-ethyl ester (87518-34-1)

Guidance literature:

Multi-step reaction with 2 steps

2: 2,6-lutidine / 140.1 °C / other temperatures, solvolyses of α-keto norbornyl trifluoroacetates and triflates, endo/exo rate ratio

With 2,6-dimethylpyridine;

DOI:10.1021/ja00362a017

Reference yield:

3-exo-hydroxynorcamphor (119565-95-6) → (S,S)-bicyclo<2.2.1>heptane-2,5-dione (145092-68-8)

Guidance literature:

With dichromate anion;

DOI:10.1021/ja00246a038

upstream raw materials:

2-diazonorbornan-3-one

Downstream raw materials:

Cyclohex-3-enecarboxylic acid 2,2,2-trifluoro-ethyl ester

(S,S)-bicyclo<2.2.1>heptane-2,5-dione