[Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃]

Base Information

• Chemical Name: [Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃]
• CAS No.: 34852-58-9
• Molecular Formula: C₅₉H₄₅O₅P₃Pt₂Ru
• Molecular Weight: 1418.15
• Mol file: 34852-58-9.mol

Synonyms:

Chemical Property of [Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃]

There total 4 articles about [Pt₂Ru(CO)₂(μ-CO)₃(PPh₃)₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

[PtRu2(CO)8(PPh3)2] → [Pt2Ru(CO)2(μ-CO)3(PPh3)3] (34852-58-9)

Guidance literature:

In dichloromethane; at 20 ℃; for 18h; UV-irradiation;

DOI:10.1016/j.poly.2013.06.011

Reference yield: 35.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + Ru3(carbonyl)11(t-butyl isocyanide) (69403-55-0,89397-37-5) → Ru3(CO)11(PPh3) (205441-17-4) + (carbonyl)7(triphenylphosphine)3(ruthenium)2platinum (82441-41-6) + [Pt2Ru(CO)2(μ-CO)3(PPh3)3] (34852-58-9) + (carbonyl)6(t-butyl isocyanide)(triphenylphosphine)(ruthenium)(platinum)2 (82441-43-8) + (carbonyl)9(t-butyl isocyanide)(triphenylphosphine)(ruthenium)2platinum

Guidance literature:

With CO; In toluene; mixing toluene solns. of Ru-complex and Pt-complex at -20°C under N2, bubbling CO through this soln. for 30 min at -20°C, colour of soln. changes to yellow-orange; sepn. of products by preparative TLC (ether/cyclohexane) gives an orange band and three further products, further sepn. of orange band gives two compds. (total yield: 19%), elem. anal.;

Reference yield: 33.0%

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + Ru3(carbonyl)11(t-butyl isocyanide) (69403-55-0,89397-37-5) → Ru3(CO)11(PPh3) (205441-17-4) + (carbonyl)7(triphenylphosphine)3(ruthenium)2platinum (82441-41-6) + [Pt2Ru(CO)2(μ-CO)3(PPh3)3] (34852-58-9) + (carbonyl)9(t-butyl isocyanide)(triphenylphosphine)(ruthenium)2platinum + (carbonyl)10(t-butyl isocyanide)(triphenylphosphine)(ruthenium)3 (83343-68-4)

Guidance literature:

In methyl cyclohexane; mixing solns. of Ru-complex and Pt-complex in methylcyclohexane at roomtemp. under N2, colour changes to deep red within 5 s, stirring at roomtemp. for 120 min; removal of solvent under vacuum, preparative TLC (acetone petroleum ether), several bands, further purification (TLC, recrystn.) affords 6 products, elem. anal.;

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

Ru₃(CO)11(PPh₂H)

Ru₃(carbonyl)11(t-butyl isocyanide)