Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl

Base Information

Chemical Name:Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl
CAS No.:1290543-32-6
Molecular Formula:C₅₂H₃₈N₄OPRu*Cl
Molecular Weight:902.397
Hs Code.:

Synonyms:

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Chemical Property of Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl

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Technology Process of Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl

There total 2 articles about Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 366-18-7
[2,2]bipyridinyl

: [(η(6)-benzene)RuCl2]2

: 144868-15-5,199796-91-3,149917-88-4
(R)-2-(diphenylphosphino)-2'-hydroxy-1,1'-binaphthyl

: 1290543-32-6,1290639-43-8
Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl

Guidance literature:: With Et₃N; In ethanol; High Pressure; under N2; in the dark; soln. of Ru complex, bipyridine and binaphthyl indry EtOH purged with N2 for 20 min; Et3N added; heated at 95°C f or 4.5 h in sealed flask; cooled to room temp.; dried under reduced pressure; column chromd. (basic aluminium oxide, CH2Cl2-MeOH 50:1 to 15:1); Et3N added to combined deep red fractions; driedunder reduced pressure; dissolved in CH2Cl2-Et2O; centrifuged; ppt. was hed (Et2O); dried under vac.;
DOI:10.1039/c0nj00787k

Reference yield: 69.0%

: 366-18-7
[2,2]bipyridinyl

: 258524-38-8,373383-22-3
[Ru(bpy)(NCMe)₃Cl]⁺Cl^-

: 795259-68-6,147486-25-7
(Ru(2,2'-bipyridine)(CH₃CN)2Cl₂)

: 144868-15-5,199796-91-3,149917-88-4
(R)-2-(diphenylphosphino)-2'-hydroxy-1,1'-binaphthyl

: 1290543-32-6,1290639-43-8
Λ-[Ru(2,2'-bipyridine)2((R)-2-diphenylphosphino-2'-hydroxy-1,1'-binaphthyl(-1H))]Cl

Guidance literature:: With K₂CO₃; In N,N-dimethyl-formamide; under Ar; in the dark; soln. of Ru complexes, binaphthyl and K2CO3 in DMF purged with Ar for 20 min; Et3N added; heated at 80°C for 4 h; cooled to room temp.; bipyridine added; heated at 90°C for 6 h; cooled to room temp.; dried under high vac.; washed (Et2O); column chromd. (basic aluminium oxide, CH2Cl2-MeOH 50:1 to 10:1 contg. 0.1% Et3N); brownish fraction concd. under reduced pressure without heating; Et2O added; centrifuged; ppt. washed (Et2O); dried under vac.;
DOI:10.1039/c0nj00787k